Endo-Selective Enyne Ring- Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes
The utility of W-alkylidene complexes for enyne ring-closing metathesis is demonstrated in a direct comparison with Mo-based analogs. Tungsten complexes lead to less alkyne oligomerization and higher levels of endo-selectivity and enantioselectivity.
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society,
2012-04-04T20:00:34Z.
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| Subjects: | |
| Online Access: | Get fulltext |