Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion

It's just a phase: A highly fluorinated compound with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of...

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Bibliographic Details
Main Authors: Lim, Jeewoo (Contributor), Swager, Timothy Manning (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Wiley-VCH Verlag GmbH & Co. KGaA, 2011-12-19T20:48:27Z.
Subjects:
Online Access:Get fulltext
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100 1 0 |a Lim, Jeewoo  |e author 
100 1 0 |a Massachusetts Institute of Technology. Department of Chemistry  |e contributor 
100 1 0 |a Swager, Timothy Manning  |e contributor 
100 1 0 |a Lim, Jeewoo  |e contributor 
100 1 0 |a Swager, Timothy Manning  |e contributor 
700 1 0 |a Swager, Timothy Manning  |e author 
245 0 0 |a Fluorous Biphase Synthesis of a Poly(p-phenyleneethynylene) and its Fluorescent Aqueous Fluorous-Phase Emulsion 
260 |b Wiley-VCH Verlag GmbH & Co. KGaA,   |c 2011-12-19T20:48:27Z. 
856 |z Get fulltext  |u http://hdl.handle.net/1721.1/67823 
520 |a It's just a phase: A highly fluorinated compound with a rigid three-dimensional architecture was synthesized as a monomer for poly(p-phenyleneethynylene)s (PPEs). Fluorous biphase reactions were applied for the synthesis of a PPE that is soluble only in fluorous solvents. A fluorous solution of the polymer could be processed into aqueous emulsions that display high fluorescence quantum yields (see picture). 
520 |a United States. Army Research Office (Institute for Soldier Nanotechnologies) 
546 |a en_US 
655 7 |a Article 
773 |t Angewandte Chemie International Edition