Enantioselective Alkenylation via Nickel-Catalyzed Cross-Coupling with Organozirconium Reagents
A new family of organometallic compounds, organozirconium reagents, are shown to serve as suitable partners in cross-coupling reactions of (activated) secondary alkyl electrophiles. Thus, the first catalytic method for coupling secondary α-bromoketones with alkenylmetal reagents has been developed,...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society,
2011-09-21T19:09:09Z.
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Online Access: | Get fulltext |