Phosphine-catalyzed asymmetric additions of malonate esters to gamma-substituted allenoates and allenamides

Because carbonyl groups are ubiquitous in organic chemistry, the ability to synthesize functionalized carbonyl compounds, particularly enantioselectively, is an important objective. We have developed a straightforward and versatile method for catalytic asymmetric carbon-carbon bond formation at the...

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Bibliographic Details
Main Authors: Sinisi, Riccardo (Contributor), Sun, Jianwei (Contributor), Fu, Gregory C. (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: National Academy of Sciences (U.S.), 2011-07-13T15:36:39Z.
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