Polymer photochemistry at the EUV wavelength

The higher energy associated with extreme ultraviolet (EUV) radiation coupled with the high absorptivity of most organic polymers at these wavelengths should lead to increased excited state population and higher quantum yields of photoproducts. Polymers representative of those commonly employed in r...

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Bibliographic Details
Main Authors: Fedynyshyn, Theodore H. (Contributor), Goodman, Russell B. (Contributor), Cabral, Alberto (Contributor), Tarrio, Charles (Author), Lucatorto, Thomas B. (Author)
Other Authors: Lincoln Laboratory (Contributor)
Format: Article
Language:English
Published: SPIE, 2011-02-14T15:16:15Z.
Subjects:
Online Access:Get fulltext
LEADER 01675 am a22002653u 4500
001 60941
042 |a dc 
100 1 0 |a Fedynyshyn, Theodore H.  |e author 
100 1 0 |a Lincoln Laboratory  |e contributor 
100 1 0 |a Fedynyshyn, Theodore H.  |e contributor 
100 1 0 |a Fedynyshyn, Theodore H.  |e contributor 
100 1 0 |a Goodman, Russell B.  |e contributor 
100 1 0 |a Cabral, Alberto  |e contributor 
700 1 0 |a Goodman, Russell B.  |e author 
700 1 0 |a Cabral, Alberto  |e author 
700 1 0 |a Tarrio, Charles  |e author 
700 1 0 |a Lucatorto, Thomas B.  |e author 
245 0 0 |a Polymer photochemistry at the EUV wavelength 
260 |b SPIE,   |c 2011-02-14T15:16:15Z. 
856 |z Get fulltext  |u http://hdl.handle.net/1721.1/60941 
520 |a The higher energy associated with extreme ultraviolet (EUV) radiation coupled with the high absorptivity of most organic polymers at these wavelengths should lead to increased excited state population and higher quantum yields of photoproducts. Polymers representative of those commonly employed in resists as well as some model polymers were selected for this study. Polymer photochemistry at EUV was catalogued as to the effect of absorbed 13.4-nm radiation on a polymer's quantum yield of chain scission (Φs) and crosslinking (Φx). In selected cases, the chain scission and crosslinking quantum yields were also compared to those previously determined at 157-, 193- and 248-nm. It was found that quantum yield values were over a magnitude greater at EUV relative to optical wavelengths. 
520 |a Intel Corporation 
546 |a en_US 
655 7 |a Article 
773 |t Proceedings of SPIE--the International Society for Optical Engineering