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141056.2 |
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|a He, Xin
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|a Looker, Benjamin G.
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|a Dinh, Kimberly T.
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|a Stubbs, Amanda W.
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|a Chen, Tianyang
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|a Meyer, Randall J.
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|a Serna, Pedro
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|a Román-Leshkov, Yuriy
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|a Lancaster, Kyle M.
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|a Dincă, Mircea
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|a Cerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFs
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|b American Chemical Society (ACS),
|c 2022-03-08T15:46:12Z.
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|z Get fulltext
|u https://hdl.handle.net/1721.1/141056.2
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|a © 2020 American Chemical Society. The rates of catalytic oxidation of cyclohexane and CO are 4 and 20 times higher, respectively, with Cu supported on a cerium-based metal-organic framework (MOF) than on the structurally analogous zirconium material. Both Ce- and Zr-based copper catalysts feature uncommon three-coordinate CuII sites bearing different nuclearities, as determined by Cu K-edge extended X-ray absorption fine structure analysis. These results offer molecular-level understanding of the metal-support interface in MOF catalysts and establish correlations with the more established literature on zirconia- and ceria-supported heterogeneous catalysis.
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|t ACS Catalysis
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