Bench-Stable Nickel Precatalysts with Heck-type Activation

Bench-Stable Nickel Precatalysts with Heck-type Activation

Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl-ene coupling reaction.

Bibliographic Details
Main Authors: Weber, Jessica M. (Author), Longstreet, Ashley R. (Author), Jamison, Timothy F (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2020-07-10T16:01:50Z.
Subjects:
Article
Online Access:Get fulltext
LEADER 01079 am a22002173u 4500
001 126128
042 |a dc 
100 1 0 |a Weber, Jessica M.  |e author 
100 1 0 |a Massachusetts Institute of Technology. Department of Chemistry  |e contributor 
700 1 0 |a Longstreet, Ashley R.  |e author 
700 1 0 |a Jamison, Timothy F  |e author 
245 0 0 |a Bench-Stable Nickel Precatalysts with Heck-type Activation 
260 |b American Chemical Society (ACS),   |c 2020-07-10T16:01:50Z. 
856 |z Get fulltext  |u https://hdl.handle.net/1721.1/126128 
520 |a Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl-ene coupling reaction. 
520 |a NIGMS (Ruth L. Kirschstein National Research Service Award, no. F32GM120852) 
520 |a National Science Foundation (grant no. CHE-0946721) 
546 |a en 
655 7 |a Article 
773 |t 10.1021/ACS.ORGANOMET.8B00351 
773 |t Organometallics 

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