Aza Diels-Alder Reactions of Nitriles, N, N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

Aza Diels-Alder Reactions of Nitriles, N, N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

Metal-free, formal [2 + 2 + 2] cycloaddition st rategies for the synthesis of polycyclic pyridine derivatives are described. The overall transformation proceeds via a two-stage pericyclic cascade mechanism. In the first step, an intramolecular propargylic ene reaction generates a vinyl-allene that i...

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Bibliographic Details
Main Authors: Hamzik, Philip Jonathan (Contributor), Goutierre, Anne-Sophie (Contributor), Sakai, Takeo (Contributor), Danheiser, Rick Lane (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2018-12-03T16:03:46Z.
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