A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO₂/ethylene Coupling

A family of cis-macrocyclic diphosphines was prepared in just three steps from white phosphorus and commercial materials using a modular synthetic approach. Alkylation of bicyclic diphosphane 3,4,8,9-tetramethyl-1,6-diphosphabicyclo(4.4.0)deca-3,8-diene, or P₂(dmb)₂ , produced phosphino-phosphonium...

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Bibliographic Details
Main Authors: Beetstra, Dirk (Author), Al-Nezari, Abdulaziz (Author), Al-Bahily, Khalid (Author), Knopf, Ioana (Contributor), Tofan, Daniel (Contributor), Cummins, Christopher C (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Royal Society of Chemistry (RSC), 2018-01-22T15:18:00Z.
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