Semibatch monomer addition as a general method to tune and enhance the mechanics of polymer networks via loop-defect control

• Main Authors: Hore, Michael J. A. (Author), Jordan, Alex M. (Author), Korley, LaShanda T. J. (Author), Gu, Yuwei (Contributor), Kawamoto, Ken (Contributor), Zhong, Mingjiang (Contributor), Chen, Mao (Contributor), Olsen, Bradley D (Contributor), Johnson, Jeremiah A. (Contributor)
• Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering (Contributor), Massachusetts Institute of Technology. Department of Chemistry (Contributor)
• Format: Article
• Language: English
• Published: National Academy of Sciences, 2018-01-19T18:42:33Z.
• Subjects: Article
• Online Access: Get fulltext

Controlling the molecular structure of amorphous cross-linked polymeric materials is a longstanding challenge. Herein, we disclose a general strategy for precise tuning of loop defects in covalent polymer gel networks. This "loop control" is achieved through a simple semibatch monomer addition protocol that can be applied to a broad range of network-forming reactions. By controlling loop defects, we demonstrate that with the same set of material precursors it is possible to tune and in several cases substantially improve network connectivity and mechanical properties (e.g., ∼600% increase in shear storage modulus). We believe that the concept of loop control via continuous reagent addition could find broad application in the synthesis of academically and industrially important cross-linked polymeric materials, such as resins and gels.
National Science Foundation (U.S.) (CHE-1334703)