Multi-electron reactivity of a cofacial di-tin(I) cryptand: partial reduction of sulfur and selenium and reversible generation of S[subscript 3][superscript ˙−]

Multi-electron reactivity of a cofacial di-tin(I) cryptand: partial reduction of sulfur and selenium and reversible generation of S[subscript 3][superscript ˙−]

Cofacial bimetallic tin(ii) ([Sn[subscript 2](mBDCA-5t)][superscript 2−], 1) and lead(ii) ([Pb[subscript 2](mBDCA-5t)][superscrip 2−], 2) complexes have been prepared by hexadeprotonation of hexacarboxamide cryptand mBDCA-5t-H[subscript 6] together with double Sn(ii) or Pb(ii) insertion. Reaction of...

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Bibliographic Details
Main Authors:	Dai, Yizhe (Author), Wu, Gang (Author), Nocera, Daniel G. (Author), Stauber, Julia M. (Contributor), Mueller, Peter (Contributor), Cummins, Christopher C (Contributor)
Other Authors:	Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format:	Article
Language:	English
Published:	Royal Society of Chemistry (RSC), 2018-01-19T15:29:02Z.
Subjects:	Article
Online Access:	Get fulltext

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