Coherent quantum transport in disordered systems: A unified polaron treatment of hopping and band-like transport

• Main Authors: Lee, Chee Kong (Contributor), Moix, Jeremy (Contributor), Cao, Jianshu (Contributor)
• Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
• Format: Article
• Language: English
• Published: American Institute of Physics (AIP), 2017-07-07T18:35:06Z.
• Subjects: Article
• Online Access: Get fulltext

Quantum transport in disordered systems is studied using a polaron-based master equation. The polaron approach is capable of bridging the results from the coherent band-like transport regime governed by the Redfield equation to incoherent hopping transport in the classical regime. A non-monotonic dependence of the diffusion coefficient is observed both as a function of temperature and system-phonon coupling strength. In the band-like transport regime, the diffusion coefficient is shown to be linearly proportional to the system-phonon coupling strength and vanishes at zero coupling due to Anderson localization. In the opposite classical hopping regime, we correctly recover the dynamics described by the Fermi's Golden Rule and establish that the scaling of the diffusion coefficient depends on the phonon bath relaxation time. In both the hopping and band-like transport regimes, it is demonstrated that at low temperature, the zero-point fluctuations of the bath lead to non-zero transport rates and hence a finite diffusion constant. Application to rubrene and other organic semiconductor materials shows a good agreement with experimental mobility data.
National Science Foundation (U.S.) (Grant CHE- 1112825)
United States. Defense Advanced Research Projects Agency (Grant N99001-10-1-4063)
Singapore. Ministry of Education
Singapore. National Research Foundation
United States. Dept. of Energy. Center for Excitonics (Award DE-SC0001088)