Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate

Bromido({2-[2-(Diphenylphosphanyl)Benzylidene]Hydrazin-1-Ylidene} (4-Methoxyanilino)Methanethiolato)Palladium(Ii) Acetone Monosolvate

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In the title compound, [PdBr(C27H23N3OPS)]·C3H6O, the coordination geometry about the PdII atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached t...

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Bibliographic Details
Main Authors: Mokthar, Khalisah Asilah (Author), Shamsuddin, Mustaffa (Author), Rosli, Mohd. Mustaqim (Author), Hoong, Kun Fun (Author)
Format: Article
Language:English
Published: International Union of Crystallography, 2012-07.
Subjects:
QD Chemistry
Online Access:Get fulltext
Description
Summary:In the title compound, [PdBr(C27H23N3OPS)]·C3H6O, the coordination geometry about the PdII atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intramolecular C-H...N hydrogen bond forms an S(6) ring motif. In the crystal, the complex molecules form infinite chains along the a-axis direction through C-H...Br interactions, and a C-H...O interaction links the main molecule with the acetone solvent molecule.

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