Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]

Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]

The title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water...

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Main Authors: Qi-Hua Zhao, Li-Nan Li, Lin Du
Format: Article
Language:English
Published: International Union of Crystallography 2009-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809013889
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spelling doaj-fff34ce82a2941ad8f4f77907da62ba82020-11-24T21:32:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m556m55610.1107/S1600536809013889Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]Qi-Hua ZhaoLi-Nan LiLin DuThe title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water molecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the CuII cations to form a two-dimensional polymeric layer. O—H...O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supramolecular framework. http://scripts.iucr.org/cgi-bin/paper?S1600536809013889
collection DOAJ
language English
format Article
sources DOAJ
author Qi-Hua Zhao
Li-Nan Li
Lin Du
spellingShingle Qi-Hua Zhao
Li-Nan Li
Lin Du
Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
Acta Crystallographica Section E
author_facet Qi-Hua Zhao
Li-Nan Li
Lin Du
author_sort Qi-Hua Zhao
title Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
title_short Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
title_full Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
title_fullStr Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
title_full_unstemmed Poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3N:O3:O5)copper(II)]
title_sort poly[diaqua(μ3-pyridine-3,5-dicarboxylato-κ3n:o3:o5)copper(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-05-01
description The title complex, [Cu(C7H3NO4)(H2O)2]n, was prepared under hydrothermal reaction conditions. In the crystal structure, the CuII cation is located on a twofold rotation axis and is coordinated by two carboxylate O atoms and one N atom from three pyridine-3,5-dicarboxylate (PDA) anions and two water molecules with a distorted trigonal–bipyramidal geometry. The tridentate PDA anion is also located on the twofold rotation axis and bridges the CuII cations to form a two-dimensional polymeric layer. O—H...O hydrogen bonding between layers links the two-dimensional layers into a three-dimensional supramolecular framework.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809013889
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AT linanli polydiaquaamp9563pyridine35dicarboxylatoamp9543no3o5copperii
AT lindu polydiaquaamp9563pyridine35dicarboxylatoamp9543no3o5copperii
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