A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE

A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE

The compound was prepared by dissolving 2-(phenylamino)pyridine (0.52 g ; 3.0 mmol) and di(methanesulfonyl)amine (0.51 g; 3.0 mmol) in 5 mL methanol. Slow partial evaporation of the solvent at low tempertaure (-30 oC) gave a yield of 0.66 g (64%) and crystals suitable for X-ray study (m.p. 150-152 o...

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Main Authors: Karna Wijaya, Iqmal Tahir, Armand Blaschette, Oliver Mours, Peter G Jones
Format: Article
Language:English
Published: Universitas Gadjah Mada 2002-03-01
Series:Indonesian Journal of Chemistry
Online Access:https://jurnal.ugm.ac.id/ijc/article/view/21935
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spelling doaj-ffdad88595184adba7ca2b7386df09f22020-11-25T01:50:47ZengUniversitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782002-03-0121737810.22146/ijc.2193515033A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATEKarna Wijaya0Iqmal Tahir1Armand Blaschette2Oliver Mours3Peter G Jones4Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, YogyakartaChemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, YogyakartaInstitute fuer Analytische und Anorganische Chemie, Technische, Universitaet zu BraunschweigInstitute fuer Analytische und Anorganische Chemie, Technische, Universitaet zu BraunschweigInstitute fuer Analytische und Anorganische Chemie, Technische, Universitaet zu BraunschweigThe compound was prepared by dissolving 2-(phenylamino)pyridine (0.52 g ; 3.0 mmol) and di(methanesulfonyl)amine (0.51 g; 3.0 mmol) in 5 mL methanol. Slow partial evaporation of the solvent at low tempertaure (-30 oC) gave a yield of 0.66 g (64%) and crystals suitable for X-ray study (m.p. 150-152 oC). The single crystal X-ray result showed that the crystal system was trikline with space group P. The crystal structure of the title compound 2-(phenylamino)pyridinium-di(methane-sulfonyl)amidate forms a robust antidromic ring motif type. The structure testifies to the persistence of the  in question, which was previously detected as a robust supramolecular synthon in 2-aminopyridinium di(benzenesulfonyl)amidate and in a series of onium di(methane-sulfonyl)amidates.   Keywords: supramolecule, hydrogen-bondhttps://jurnal.ugm.ac.id/ijc/article/view/21935
collection DOAJ
language English
format Article
sources DOAJ
author Karna Wijaya
Iqmal Tahir
Armand Blaschette
Oliver Mours
Peter G Jones
spellingShingle Karna Wijaya
Iqmal Tahir
Armand Blaschette
Oliver Mours
Peter G Jones
A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE
Indonesian Journal of Chemistry
author_facet Karna Wijaya
Iqmal Tahir
Armand Blaschette
Oliver Mours
Peter G Jones
author_sort Karna Wijaya
title A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE
title_short A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE
title_full A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE
title_fullStr A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE
title_full_unstemmed A ROBUST EIGHT–MEMBERED RING MOTIF IN THE HYDROGEN-BONDED STRUCTURE OF -(PHENYLAMINO)PYRIDINIUM- DI(METHANESULFONYL)AMIDATE
title_sort robust eight–membered ring motif in the hydrogen-bonded structure of -(phenylamino)pyridinium- di(methanesulfonyl)amidate
publisher Universitas Gadjah Mada
series Indonesian Journal of Chemistry
issn 1411-9420
2460-1578
publishDate 2002-03-01
description The compound was prepared by dissolving 2-(phenylamino)pyridine (0.52 g ; 3.0 mmol) and di(methanesulfonyl)amine (0.51 g; 3.0 mmol) in 5 mL methanol. Slow partial evaporation of the solvent at low tempertaure (-30 oC) gave a yield of 0.66 g (64%) and crystals suitable for X-ray study (m.p. 150-152 oC). The single crystal X-ray result showed that the crystal system was trikline with space group P. The crystal structure of the title compound 2-(phenylamino)pyridinium-di(methane-sulfonyl)amidate forms a robust antidromic ring motif type. The structure testifies to the persistence of the  in question, which was previously detected as a robust supramolecular synthon in 2-aminopyridinium di(benzenesulfonyl)amidate and in a series of onium di(methane-sulfonyl)amidates.   Keywords: supramolecule, hydrogen-bond
url https://jurnal.ugm.ac.id/ijc/article/view/21935
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