A Comparative Review of Metal Oxide Surface Coatings on Three Families of Cathode Materials for Lithium Ion Batteries

• Main Authors: Thabang Ronny Somo, Tumiso Eminence Mabokela, Daniel Malesela Teffu, Tshepo Kgokane Sekgobela, Brian Ramogayana, Mpitloane Joseph Hato, Kwena Desmond Modibane
• Format: Article
• Language: English
• Published: MDPI AG 2021-06-01
• Series: Coatings
• Subjects: lithium-ion batteries; electrochemical performance; metal dissolution; metal oxide coating
• Online Access: https://www.mdpi.com/2079-6412/11/7/744

In the recent years, lithium-ion batteries have prevailed and dominated as the primary power sources for mobile electronic applications. Equally, their use in electric resources of transportation and other high-level applications is hindered to some certain extent. As a result, innovative fabrication of lithium-ion batteries based on best performing cathode materials should be developed as electrochemical performances of batteries depends largely on the electrode materials. Elemental doping and coating of cathode materials as a way of upgrading Li-ion batteries have gained interest and have modified most of the commonly used cathode materials. This has resulted in enhanced penetration of Li-ions, ionic mobility, electric conductivity and cyclability, with lesser capacity fading compared to traditional parent materials. The current paper reviews the role and effect of metal oxides as coatings for improvement of cathode materials in Li-ion batteries. For layered cathode materials, a clear evaluation of how metal oxide coatings sweep of metal ion dissolution, phase transitions and hydrofluoric acid attacks is detailed. Whereas the effective ways in which metal oxides suppress metal ion dissolution and capacity fading related to spinel cathode materials are explained. Lastly, challenges faced by olivine-type cathode materials, namely; low electronic conductivity and diffusion coefficient of Li⁺ ion, are discussed and recent findings on how metal oxide coatings could curb such limitations are outlined.