Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study
The asymmetric unit of the title compound, [Cd(C30H31N3O6)2](PF6)2·3H2O, contains one half-cation with the CdII center situated on a twofold rotational axis, one hexafluoridophosphate anion and two uncoordinated water molecules, one of which is also situated on a twofold rotational axis...
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809040926 |
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doaj-ff7eee9934cb427fa0b5632e3593d0d22020-11-25T01:33:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1349m135010.1107/S1600536809040926Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder studyNadezhda M. KurochkinaAndrey S. KuzovlevTamara P. PuryaevaYurii A. VelikodnyVladimir V. ChernyshevThe asymmetric unit of the title compound, [Cd(C30H31N3O6)2](PF6)2·3H2O, contains one half-cation with the CdII center situated on a twofold rotational axis, one hexafluoridophosphate anion and two uncoordinated water molecules, one of which is also situated on a twofold rotational axis. The cations are associated into columns along the a axis through π–π interactions between the pyridine and benzene rings, with a centroid–centroid distance of 3.72 (5) Å. Intermolecular O—H...O, C—H...O and C—H...F hydrogen bonds consolidate the crystal packing. http://scripts.iucr.org/cgi-bin/paper?S1600536809040926 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Nadezhda M. Kurochkina Andrey S. Kuzovlev Tamara P. Puryaeva Yurii A. Velikodny Vladimir V. Chernyshev |
| spellingShingle |
Nadezhda M. Kurochkina Andrey S. Kuzovlev Tamara P. Puryaeva Yurii A. Velikodny Vladimir V. Chernyshev Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study Acta Crystallographica Section E |
| author_facet |
Nadezhda M. Kurochkina Andrey S. Kuzovlev Tamara P. Puryaeva Yurii A. Velikodny Vladimir V. Chernyshev |
| author_sort |
Nadezhda M. Kurochkina |
| title |
Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_short |
Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_full |
Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_fullStr |
Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_full_unstemmed |
Bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(II) bis(hexafluoridophosphate) trihydrate: a powder study |
| title_sort |
bis{4′-[(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-15-yl)methoxy]-2,2′:6′,2′′-terpyridine}cadmium(ii) bis(hexafluoridophosphate) trihydrate: a powder study |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-11-01 |
| description |
The asymmetric unit of the title compound, [Cd(C30H31N3O6)2](PF6)2·3H2O, contains one half-cation with the CdII center situated on a twofold rotational axis, one hexafluoridophosphate anion and two uncoordinated water molecules, one of which is also situated on a twofold rotational axis. The cations are associated into columns along the a axis through π–π interactions between the pyridine and benzene rings, with a centroid–centroid distance of 3.72 (5) Å. Intermolecular O—H...O, C—H...O and C—H...F hydrogen bonds consolidate the crystal packing. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809040926 |
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