Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge

A charcoal was produced from primary pulp mill sludge and then used for the adsorptive removal of diclofenac, salicylic acid, ibuprofen and acetaminophen. A main aim was to assess the utilization of this material for the tertiary treatment of sewage. For this purpose, the adsorption of the selected...

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Main Authors: R.N. Coimbra, V. Calisto, C.I.A. Ferreira, V.I. Esteves, M. Otero
Format: Article
Language:English
Published: Elsevier 2019-12-01
Series:Arabian Journal of Chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535215003299
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spelling doaj-ff5d89e59a5b46f299500af3c7624dd82020-11-25T02:45:28ZengElsevierArabian Journal of Chemistry1878-53522019-12-0112836113620Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludgeR.N. Coimbra0V. Calisto1C.I.A. Ferreira2V.I. Esteves3M. Otero4Department of Applied Chemistry and Physics, Institute of Environment, Natural Resources and Biodiversity (IMARENABIO), University of León, León 24071, SpainDepartment of Chemistry and CESAM (Centre for Environmental and Marine Studies), University of Aveiro, Campus de Santiago, 3810-193 Aveiro, PortugalDepartment of Chemistry and CESAM (Centre for Environmental and Marine Studies), University of Aveiro, Campus de Santiago, 3810-193 Aveiro, PortugalDepartment of Chemistry and CESAM (Centre for Environmental and Marine Studies), University of Aveiro, Campus de Santiago, 3810-193 Aveiro, PortugalDepartment of Applied Chemistry and Physics, Institute of Environment, Natural Resources and Biodiversity (IMARENABIO), University of León, León 24071, Spain; Corresponding author.A charcoal was produced from primary pulp mill sludge and then used for the adsorptive removal of diclofenac, salicylic acid, ibuprofen and acetaminophen. A main aim was to assess the utilization of this material for the tertiary treatment of sewage. For this purpose, the adsorption of the selected pharmaceuticals from the secondary effluent of a sewage treatment plant (STP) was compared with their adsorption from ultrapure water. Differences in the adsorption kinetics and equilibrium were evident between the four pharmaceuticals considered. However, differences between the adsorption from the two aqueous matrixes considered were negligible. It was hypothesized that synergetic microorganism removal compensated the competitive effects in wastewater. Keywords: Paper sludge, Pyrolysis, Wastewater treatment, Emerging contaminants, Pain reliever, Sorptionhttp://www.sciencedirect.com/science/article/pii/S1878535215003299
collection DOAJ
language English
format Article
sources DOAJ
author R.N. Coimbra
V. Calisto
C.I.A. Ferreira
V.I. Esteves
M. Otero
spellingShingle R.N. Coimbra
V. Calisto
C.I.A. Ferreira
V.I. Esteves
M. Otero
Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge
Arabian Journal of Chemistry
author_facet R.N. Coimbra
V. Calisto
C.I.A. Ferreira
V.I. Esteves
M. Otero
author_sort R.N. Coimbra
title Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge
title_short Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge
title_full Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge
title_fullStr Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge
title_full_unstemmed Removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge
title_sort removal of pharmaceuticals from municipal wastewater by adsorption onto pyrolyzed pulp mill sludge
publisher Elsevier
series Arabian Journal of Chemistry
issn 1878-5352
publishDate 2019-12-01
description A charcoal was produced from primary pulp mill sludge and then used for the adsorptive removal of diclofenac, salicylic acid, ibuprofen and acetaminophen. A main aim was to assess the utilization of this material for the tertiary treatment of sewage. For this purpose, the adsorption of the selected pharmaceuticals from the secondary effluent of a sewage treatment plant (STP) was compared with their adsorption from ultrapure water. Differences in the adsorption kinetics and equilibrium were evident between the four pharmaceuticals considered. However, differences between the adsorption from the two aqueous matrixes considered were negligible. It was hypothesized that synergetic microorganism removal compensated the competitive effects in wastewater. Keywords: Paper sludge, Pyrolysis, Wastewater treatment, Emerging contaminants, Pain reliever, Sorption
url http://www.sciencedirect.com/science/article/pii/S1878535215003299
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