Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]

Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]

In the title 1:1 silver 4-aminobenzenesulfonate adduct with triphenylphosphine, [Ag(C6H6NO3S)(C18H15P)]n, the sulfonate –SO3 unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag2O2 rhombus. The Ag+ cation adopts a considerably distorte...

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Main Authors: Omid Sadeghi, Mostafa M. Amini, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810024207
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spelling doaj-fe84629fa2b544039bde7fff3ab83a652020-11-24T21:50:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m855m85610.1107/S1600536810024207Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]Omid SadeghiMostafa M. AminiSeik Weng NgIn the title 1:1 silver 4-aminobenzenesulfonate adduct with triphenylphosphine, [Ag(C6H6NO3S)(C18H15P)]n, the sulfonate –SO3 unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag2O2 rhombus. The Ag+ cation adopts a considerably distorted a tetrahedral coordination. In the crystal, adjacent binuclear molecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis. http://scripts.iucr.org/cgi-bin/paper?S1600536810024207
collection DOAJ
language English
format Article
sources DOAJ
author Omid Sadeghi
Mostafa M. Amini
Seik Weng Ng
spellingShingle Omid Sadeghi
Mostafa M. Amini
Seik Weng Ng
Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]
Acta Crystallographica Section E
author_facet Omid Sadeghi
Mostafa M. Amini
Seik Weng Ng
author_sort Omid Sadeghi
title Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]
title_short Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]
title_full Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]
title_fullStr Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]
title_full_unstemmed Poly[(μ3-4-aminobenzenesulfonato-κ3N:O:O)(triphenylphosphine-κP)silver(I)]
title_sort poly[(μ3-4-aminobenzenesulfonato-κ3n:o:o)(triphenylphosphine-κp)silver(i)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description In the title 1:1 silver 4-aminobenzenesulfonate adduct with triphenylphosphine, [Ag(C6H6NO3S)(C18H15P)]n, the sulfonate –SO3 unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag2O2 rhombus. The Ag+ cation adopts a considerably distorted a tetrahedral coordination. In the crystal, adjacent binuclear molecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810024207
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AT mostafamamini polyamp95634aminobenzenesulfonatoamp9543nootriphenylphosphineamp954psilveri
AT seikwengng polyamp95634aminobenzenesulfonatoamp9543nootriphenylphosphineamp954psilveri
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