Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature

Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature

The compound, C6H7N3OS, has been prepared and characterized by condensation between thiosemicarbazide and furan-2-carbaldehyde and its structure was elucidated by x-ray analysis (at 150 K), NMR and IR spectroscopy methods (at ambient temperature). It crystallizes in the monoclinic space group P21/c...

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Main Authors: Alireza Abbasi, Shokoofeh Geranmayeh, Ali Naghi Taheri, Hashem Shahroosvand, Mohsen Shabani
Format: Article
Language:English
Published: Hindawi Limited 2010-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2010/347576
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spelling doaj-fe82aa476f154704a31fdcc38fd2e9612020-11-24T22:53:46ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102010-01-017S1S294S29810.1155/2010/347576Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low TemperatureAlireza Abbasi0Shokoofeh Geranmayeh1Ali Naghi Taheri2Hashem Shahroosvand3Mohsen Shabani4School of Chemistry, College of Science, University of Tehran, Tehran, IranSchool of Chemistry, College of Science, University of Tehran, Tehran, IranSchool of Chemistry, Shahrood University of Technology, IranDepartment of Chemistry, Zanjan University, Zanjan, IranChemistry Department, Islamic Azad University, Varamin-Pishva Branch, Tehran, IranThe compound, C6H7N3OS, has been prepared and characterized by condensation between thiosemicarbazide and furan-2-carbaldehyde and its structure was elucidated by x-ray analysis (at 150 K), NMR and IR spectroscopy methods (at ambient temperature). It crystallizes in the monoclinic space group P21/c (No. 14), a = 13.5099(3) Å, b = 5.67430(10) Å, c = 23.4755(6) Å, β= 117.367(2)°, V = 1598.20(7) Å3 and Z = 8. The crystal structure was solved and refined to R = 0.0290 with 2942 unique reflections. No significant π-π interactions are found in the crystal structure. There are C-H…π interactions and also different weak hydrogen bonds, stabilizing the three dimensional crystal structure.http://dx.doi.org/10.1155/2010/347576
collection DOAJ
language English
format Article
sources DOAJ
author Alireza Abbasi
Shokoofeh Geranmayeh
Ali Naghi Taheri
Hashem Shahroosvand
Mohsen Shabani
spellingShingle Alireza Abbasi
Shokoofeh Geranmayeh
Ali Naghi Taheri
Hashem Shahroosvand
Mohsen Shabani
Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature
E-Journal of Chemistry
author_facet Alireza Abbasi
Shokoofeh Geranmayeh
Ali Naghi Taheri
Hashem Shahroosvand
Mohsen Shabani
author_sort Alireza Abbasi
title Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature
title_short Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature
title_full Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature
title_fullStr Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature
title_full_unstemmed Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature
title_sort synthesis and characterization of (z)-furan-2-carbaldehyde thiosemicarbazone at low temperature
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2010-01-01
description The compound, C6H7N3OS, has been prepared and characterized by condensation between thiosemicarbazide and furan-2-carbaldehyde and its structure was elucidated by x-ray analysis (at 150 K), NMR and IR spectroscopy methods (at ambient temperature). It crystallizes in the monoclinic space group P21/c (No. 14), a = 13.5099(3) Å, b = 5.67430(10) Å, c = 23.4755(6) Å, β= 117.367(2)°, V = 1598.20(7) Å3 and Z = 8. The crystal structure was solved and refined to R = 0.0290 with 2942 unique reflections. No significant π-π interactions are found in the crystal structure. There are C-H…π interactions and also different weak hydrogen bonds, stabilizing the three dimensional crystal structure.
url http://dx.doi.org/10.1155/2010/347576
work_keys_str_mv AT alirezaabbasi synthesisandcharacterizationofzfuran2carbaldehydethiosemicarbazoneatlowtemperature
AT shokoofehgeranmayeh synthesisandcharacterizationofzfuran2carbaldehydethiosemicarbazoneatlowtemperature
AT alinaghitaheri synthesisandcharacterizationofzfuran2carbaldehydethiosemicarbazoneatlowtemperature
AT hashemshahroosvand synthesisandcharacterizationofzfuran2carbaldehydethiosemicarbazoneatlowtemperature
AT mohsenshabani synthesisandcharacterizationofzfuran2carbaldehydethiosemicarbazoneatlowtemperature
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