| Summary: | Citizens’ wellbeing is mainly threatened by poor air quality and local overheating due to human-activity concentration and land-cover/surface modification in urban areas. Peculiar morphology and metabolism of urban areas lead to the well-known urban-heat-island effect, characterized by higher air temperature in cities than in their surroundings. The environmental mapping of the urban outdoors at the pedestrian height could be a key tool to identify risky areas for humans in terms of both poor-air-quality exposure and thermal comfort. This study proposes urban environment investigation through a wearable miniaturized weather station to get the spatial distribution of key parameters according to the citizens’ perspective. The innovative system monitors and traces the field values of carbon dioxide (CO<sub>2</sub>) concentration, such as air temperature and wind-speed values, which have been demonstrated to be related to outdoor wellbeing. The presented monitoring campaign focused on a two-way, two-lane road in Rome (Italy) during traffic rush hours on both working days and weekends. Collected data were analyzed with respect to timing and position, and possible correlations among different variables were examined. Results demonstrated the wearable system capability to catch pedestrian-exposure variability in terms of CO<sub>2</sub> concentration and local overheating due to urban structure, highlighting potentials in the citizens’ involvement as observation vectors to extensively monitor urban environmental quality.
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