Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate

Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate

In the title compound, [ReBr(C14H11N3O)(CO)3]·CH2Cl2, the coordination geometry of the ReI atom is a distorted ReC3N2Br octahedron with the carbonyl C atoms in a fac arrangement. Within the 2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole ligand, the dihedral angles between the oxadiazole ri...

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Main Authors: Hua-ru Cao, Ying Guan, Zhen-jun Si, Yan-wei Li, Lin-Fang Shi
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681004969X
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spelling doaj-fdfa3be8c67f4341bf104345898457b52020-11-25T00:57:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m9m1010.1107/S160053681004969XBromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvateHua-ru CaoYing GuanZhen-jun SiYan-wei LiLin-Fang ShiIn the title compound, [ReBr(C14H11N3O)(CO)3]·CH2Cl2, the coordination geometry of the ReI atom is a distorted ReC3N2Br octahedron with the carbonyl C atoms in a fac arrangement. Within the 2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole ligand, the dihedral angles between the oxadiazole ring and the pyridine (py) and benzene (bz) rings are 1.7 (2) and 7.1 (2)°, respectively, and the dihedral angle between the py and bz rings is 5.5 (2)°. In the crystal, aromatic π–π stacking between the oxadiazole rings of adjacent molecules [centroid–centroid separation = 3.465 (3) Å] is seen. http://scripts.iucr.org/cgi-bin/paper?S160053681004969X
collection DOAJ
language English
format Article
sources DOAJ
author Hua-ru Cao
Ying Guan
Zhen-jun Si
Yan-wei Li
Lin-Fang Shi
spellingShingle Hua-ru Cao
Ying Guan
Zhen-jun Si
Yan-wei Li
Lin-Fang Shi
Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate
Acta Crystallographica Section E
author_facet Hua-ru Cao
Ying Guan
Zhen-jun Si
Yan-wei Li
Lin-Fang Shi
author_sort Hua-ru Cao
title Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate
title_short Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate
title_full Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate
title_fullStr Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate
title_full_unstemmed Bromidotricarbonyl[2-(pyridin-2-yl-κN)-5-p-tolyl-1,3,4-oxadiazole-κN3]rhenium(I) dichloromethane monosolvate
title_sort bromidotricarbonyl[2-(pyridin-2-yl-κn)-5-p-tolyl-1,3,4-oxadiazole-κn3]rhenium(i) dichloromethane monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description In the title compound, [ReBr(C14H11N3O)(CO)3]·CH2Cl2, the coordination geometry of the ReI atom is a distorted ReC3N2Br octahedron with the carbonyl C atoms in a fac arrangement. Within the 2-(pyridin-2-yl)-5-p-tolyl-1,3,4-oxadiazole ligand, the dihedral angles between the oxadiazole ring and the pyridine (py) and benzene (bz) rings are 1.7 (2) and 7.1 (2)°, respectively, and the dihedral angle between the py and bz rings is 5.5 (2)°. In the crystal, aromatic π–π stacking between the oxadiazole rings of adjacent molecules [centroid–centroid separation = 3.465 (3) Å] is seen.
url http://scripts.iucr.org/cgi-bin/paper?S160053681004969X
work_keys_str_mv AT huarucao bromidotricarbonyl2pyridin2ylamp954n5ptolyl134oxadiazoleamp954n3rheniumidichloromethanemonosolvate
AT yingguan bromidotricarbonyl2pyridin2ylamp954n5ptolyl134oxadiazoleamp954n3rheniumidichloromethanemonosolvate
AT zhenjunsi bromidotricarbonyl2pyridin2ylamp954n5ptolyl134oxadiazoleamp954n3rheniumidichloromethanemonosolvate
AT yanweili bromidotricarbonyl2pyridin2ylamp954n5ptolyl134oxadiazoleamp954n3rheniumidichloromethanemonosolvate
AT linfangshi bromidotricarbonyl2pyridin2ylamp954n5ptolyl134oxadiazoleamp954n3rheniumidichloromethanemonosolvate
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