Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates

Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates

A simple, chemoselective transfer hydrogenation of aryl aldehydes with the aid of Amberlite® resin formate (ARF), a stable H-donor, in the presence of catalytic ruthenium trichloride is described. Aromatic aldehydes and 1,2-diketones are reduced efficiently and selectively, while aryl ketones remain...

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Main Authors: Basudeb Basu, Bablee Mandal, Sajal Das, Pralay Das, Ashis K. Nanda
Format: Article
Language:English
Published: Beilstein-Institut 2008-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Amberlite® resins
chemoselectivity
hydrogen transfer
reduction of carbonyl group
ruthenium chloride
Online Access:https://doi.org/10.3762/bjoc.4.53
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spelling doaj-fdc585e8eb3b430fb145f5b386760b942021-02-02T07:54:14ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972008-12-01415310.3762/bjoc.4.531860-5397-4-53Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formatesBasudeb Basu0Bablee Mandal1Sajal Das2Pralay Das3Ashis K. Nanda4Department of Chemistry, University of North Bengal, Darjeeling 734 013, IndiaDepartment of Chemistry, University of North Bengal, Darjeeling 734 013, IndiaDepartment of Chemistry, University of North Bengal, Darjeeling 734 013, IndiaDepartment of Chemistry, University of North Bengal, Darjeeling 734 013, IndiaDepartment of Chemistry, University of North Bengal, Darjeeling 734 013, IndiaA simple, chemoselective transfer hydrogenation of aryl aldehydes with the aid of Amberlite® resin formate (ARF), a stable H-donor, in the presence of catalytic ruthenium trichloride is described. Aromatic aldehydes and 1,2-diketones are reduced efficiently and selectively, while aryl ketones remain unchanged. Several other potentially reducible groups attached to the aromatic moiety are unaffected.https://doi.org/10.3762/bjoc.4.53Amberlite® resinschemoselectivityhydrogen transferreduction of carbonyl groupruthenium chloride
collection DOAJ
language English
format Article
sources DOAJ
author Basudeb Basu
Bablee Mandal
Sajal Das
Pralay Das
Ashis K. Nanda
spellingShingle Basudeb Basu
Bablee Mandal
Sajal Das
Pralay Das
Ashis K. Nanda
Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
Beilstein Journal of Organic Chemistry
Amberlite® resins
chemoselectivity
hydrogen transfer
reduction of carbonyl group
ruthenium chloride
author_facet Basudeb Basu
Bablee Mandal
Sajal Das
Pralay Das
Ashis K. Nanda
author_sort Basudeb Basu
title Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
title_short Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
title_full Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
title_fullStr Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
title_full_unstemmed Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
title_sort chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2008-12-01
description A simple, chemoselective transfer hydrogenation of aryl aldehydes with the aid of Amberlite® resin formate (ARF), a stable H-donor, in the presence of catalytic ruthenium trichloride is described. Aromatic aldehydes and 1,2-diketones are reduced efficiently and selectively, while aryl ketones remain unchanged. Several other potentially reducible groups attached to the aromatic moiety are unaffected.
topic Amberlite® resins
chemoselectivity
hydrogen transfer
reduction of carbonyl group
ruthenium chloride
url https://doi.org/10.3762/bjoc.4.53
work_keys_str_mv AT basudebbasu chemoselectivereductionofaldehydesbyrutheniumtrichlorideandresinboundformates
AT bableemandal chemoselectivereductionofaldehydesbyrutheniumtrichlorideandresinboundformates
AT sajaldas chemoselectivereductionofaldehydesbyrutheniumtrichlorideandresinboundformates
AT pralaydas chemoselectivereductionofaldehydesbyrutheniumtrichlorideandresinboundformates
AT ashisknanda chemoselectivereductionofaldehydesbyrutheniumtrichlorideandresinboundformates
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