Estimating the chloride transport in cement paste

A method was developed to measure the diffusion coefficient of chloride ions in cement paste based on an analytical solution to Fick’s 2nd law in a cylindrical coordinate system. This natural method yielded diffusivity results within as little as a month. Testing time was reduced by exploiting the t...

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Bibliographic Details
Main Author: A. Princigallo
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Científicas 2012-06-01
Series:Materiales de Construccion
Subjects:
Online Access:http://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/691
Description
Summary:A method was developed to measure the diffusion coefficient of chloride ions in cement paste based on an analytical solution to Fick’s 2nd law in a cylindrical coordinate system. This natural method yielded diffusivity results within as little as a month. Testing time was reduced by exploiting the three-dimensional inward flux in the specimen. In an attempt to determine the saturation concentration, dense portland cement pastes were exposed to a concentrated chloride solution. The method proved to be useful for exploring cement hydration-induced changes in the diffusion coefficient of cement paste.
ISSN:0465-2746
1988-3226