trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)

trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)

The molecular structure of the title compound, [Mo2(CH3COO)2Cl2(C30H25NP2)]·0.3CH2Cl2·1.7C4H8O, features an Mo—Mo dumbbell bridged by two acetate groups which are trans to each other. Perpendicular to the plane spanned by the acetate groups, the Ph2PN(Ph)PPh2...

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Bibliographic Details
Main Authors: Marko Hapke, Anina Wöhl, Stephan Peitz, Anke Spannenberg, Uwe Rosenthal
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809007016
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spelling doaj-fd7297134db149a3ad8f841ce8c774432020-11-24T21:55:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m357m35710.1107/S1600536809007016trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)Marko HapkeAnina WöhlStephan PeitzAnke SpannenbergUwe RosenthalThe molecular structure of the title compound, [Mo2(CH3COO)2Cl2(C30H25NP2)]·0.3CH2Cl2·1.7C4H8O, features an Mo—Mo dumbbell bridged by two acetate groups which are trans to each other. Perpendicular to the plane spanned by the acetate groups, the Ph2PN(Ph)PPh2 ligand bridges both Mo atoms, having a P—N—P angle of 114.09 (19)°. In a trans position to the PNP ligand are two Cl atoms, one on each molybdenum centre. The Mo—Mo bond distance is 2.1161 (9) Å, within the range known for Mo—Mo quadruple bonds. The Mo complex is located on a crystallographic twofold rotation axis which runs through the N—C bond of the ligand. The site occupation factors of the disordered solvent molecules were fixed to 0.15 for dichloromethane and 0.85 for tetrahydrofuran. http://scripts.iucr.org/cgi-bin/paper?S1600536809007016
collection DOAJ
language English
format Article
sources DOAJ
author Marko Hapke
Anina Wöhl
Stephan Peitz
Anke Spannenberg
Uwe Rosenthal
spellingShingle Marko Hapke
Anina Wöhl
Stephan Peitz
Anke Spannenberg
Uwe Rosenthal
trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)
Acta Crystallographica Section E
author_facet Marko Hapke
Anina Wöhl
Stephan Peitz
Anke Spannenberg
Uwe Rosenthal
author_sort Marko Hapke
title trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)
title_short trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)
title_full trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)
title_fullStr trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)
title_full_unstemmed trans-Di-μ-acetato-[μ-N,N-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(II)](Mo—Mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)
title_sort trans-di-μ-acetato-[μ-n,n-bis(diphenylphosphino)aniline]bis[chloridomolybdenum(ii)](mo—mo)–dichloromethane–tetrahydrofuran (1/0.3/1.7)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description The molecular structure of the title compound, [Mo2(CH3COO)2Cl2(C30H25NP2)]·0.3CH2Cl2·1.7C4H8O, features an Mo—Mo dumbbell bridged by two acetate groups which are trans to each other. Perpendicular to the plane spanned by the acetate groups, the Ph2PN(Ph)PPh2 ligand bridges both Mo atoms, having a P—N—P angle of 114.09 (19)°. In a trans position to the PNP ligand are two Cl atoms, one on each molybdenum centre. The Mo—Mo bond distance is 2.1161 (9) Å, within the range known for Mo—Mo quadruple bonds. The Mo complex is located on a crystallographic twofold rotation axis which runs through the N—C bond of the ligand. The site occupation factors of the disordered solvent molecules were fixed to 0.15 for dichloromethane and 0.85 for tetrahydrofuran.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809007016
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AT aninawamp246hl transdiamp956acetatoamp956nnbisdiphenylphosphinoanilinebischloridomolybdenumiimoamp8212moamp8211dichloromethaneamp8211tetrahydrofuran10317
AT stephanpeitz transdiamp956acetatoamp956nnbisdiphenylphosphinoanilinebischloridomolybdenumiimoamp8212moamp8211dichloromethaneamp8211tetrahydrofuran10317
AT ankespannenberg transdiamp956acetatoamp956nnbisdiphenylphosphinoanilinebischloridomolybdenumiimoamp8212moamp8211dichloromethaneamp8211tetrahydrofuran10317
AT uwerosenthal transdiamp956acetatoamp956nnbisdiphenylphosphinoanilinebischloridomolybdenumiimoamp8212moamp8211dichloromethaneamp8211tetrahydrofuran10317
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