Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate

Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate

In the title methanol disolvate complex, [Ni4(C14H16N3O4)2(ClO4)2(C10H8N2)2]·2CH3OH, the neutral tetranickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and carboxyl groups a...

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Main Authors: Zhongjun Gao, Chunliang Tian
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680905017X
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spelling doaj-fd0843d32c2b419483da17d25f70f2f12020-11-25T01:36:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1691m169110.1107/S160053680905017XBis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvateZhongjun GaoChunliang TianIn the title methanol disolvate complex, [Ni4(C14H16N3O4)2(ClO4)2(C10H8N2)2]·2CH3OH, the neutral tetranickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and carboxyl groups are 5.227 (9) and 5.268 (6) Å, respectively. In the crystal structure, a two-dimensional supramolecular network structure involving O—H...O and C—H...O hydrogen bonding is observed. http://scripts.iucr.org/cgi-bin/paper?S160053680905017X
collection DOAJ
language English
format Article
sources DOAJ
author Zhongjun Gao
Chunliang Tian
spellingShingle Zhongjun Gao
Chunliang Tian
Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate
Acta Crystallographica Section E
author_facet Zhongjun Gao
Chunliang Tian
author_sort Zhongjun Gao
title Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate
title_short Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate
title_full Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate
title_fullStr Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate
title_full_unstemmed Bis(2,2′-bipyridine)bis{μ3-cis-N-(2-carboxylatophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(II) methanol disolvate
title_sort bis(2,2′-bipyridine)bis{μ3-cis-n-(2-carboxylatophenyl)-n′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato)tetranickel(ii) methanol disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description In the title methanol disolvate complex, [Ni4(C14H16N3O4)2(ClO4)2(C10H8N2)2]·2CH3OH, the neutral tetranickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and carboxyl groups are 5.227 (9) and 5.268 (6) Å, respectively. In the crystal structure, a two-dimensional supramolecular network structure involving O—H...O and C—H...O hydrogen bonding is observed.
url http://scripts.iucr.org/cgi-bin/paper?S160053680905017X
work_keys_str_mv AT zhongjungao bis22amp8242bipyridinebisamp9563cisn2carboxylatophenylnamp82423dimethylaminopropyloxamidato3amp8722bisperchloratotetranickeliimethanoldisolvate
AT chunliangtian bis22amp8242bipyridinebisamp9563cisn2carboxylatophenylnamp82423dimethylaminopropyloxamidato3amp8722bisperchloratotetranickeliimethanoldisolvate
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