1-Chloro-1-[(Z)-2-phenylhydrazin-1-ylidene]propan-2-one

The title compound, C9H9ClN2O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N—H...O and C—H...O hydrogen...

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Bibliographic Details
Main Authors: Hatem A. Abdel-Aziz, Tze Shyang Chia, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812028759
Description
Summary:The title compound, C9H9ClN2O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N—H...O and C—H...O hydrogen bonds, which leads to [010] infinite chains incorporating R21(6) loops. The crystal structure also features a C—H...π interaction.
ISSN:1600-5368