Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)

Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)

The asymmetric unit of the title complex, [Co(DMF)6](ClO4)2 (DMF = N,N-dimethylformamide, C3H7NO), consists of two half complex cations with the Co2+ metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co2+ ion is coordinated by six molecules of DMF in...

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Main Authors: Edwin Weber, Florian O. R. L. Mertens, Tony Böhle, Frank Eissmann
Format: Article
Language:English
Published: International Union of Crystallography 2010-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681000454X
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spelling doaj-fb9779aaca3b4f4284278c6c34a75ad62020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663m279m27910.1107/S160053681000454XHexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)Edwin WeberFlorian O. R. L. MertensTony BöhleFrank EissmannThe asymmetric unit of the title complex, [Co(DMF)6](ClO4)2 (DMF = N,N-dimethylformamide, C3H7NO), consists of two half complex cations with the Co2+ metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co2+ ion is coordinated by six molecules of DMF in a slightly distorted octahedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C—H...O hydrogen-bonding interactions. http://scripts.iucr.org/cgi-bin/paper?S160053681000454X
collection DOAJ
language English
format Article
sources DOAJ
author Edwin Weber
Florian O. R. L. Mertens
Tony Böhle
Frank Eissmann
spellingShingle Edwin Weber
Florian O. R. L. Mertens
Tony Böhle
Frank Eissmann
Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)
Acta Crystallographica Section E
author_facet Edwin Weber
Florian O. R. L. Mertens
Tony Böhle
Frank Eissmann
author_sort Edwin Weber
title Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)
title_short Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)
title_full Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)
title_fullStr Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)
title_full_unstemmed Hexakis(N,N-dimethylformamide-κO)cobalt(II) bis(perchlorate)
title_sort hexakis(n,n-dimethylformamide-κo)cobalt(ii) bis(perchlorate)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-03-01
description The asymmetric unit of the title complex, [Co(DMF)6](ClO4)2 (DMF = N,N-dimethylformamide, C3H7NO), consists of two half complex cations with the Co2+ metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co2+ ion is coordinated by six molecules of DMF in a slightly distorted octahedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C—H...O hydrogen-bonding interactions.
url http://scripts.iucr.org/cgi-bin/paper?S160053681000454X
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AT florianorlmertens hexakisnndimethylformamideamp954ocobaltiibisperchlorate
AT tonybamp246hle hexakisnndimethylformamideamp954ocobaltiibisperchlorate
AT frankeissmann hexakisnndimethylformamideamp954ocobaltiibisperchlorate
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