Integration of Stable Ionic Liquid-Based Nanofluids into Polymer Membranes. Part I: Membrane Synthesis and Characterization

• Main Authors: Carolina Hermida-Merino, Fernando Pardo, Gabriel Zarca, João M. M. Araújo, Ane Urtiaga, Manuel M. Piñeiro, Ana B. Pereiro
• Format: Article
• Language: English
• Published: MDPI AG 2021-02-01
• Series: Nanomaterials
• Subjects: materials for gas separation; ionanofluids; functionalized pebax^®1657 membrane; thermal and morphological properties
• Online Access: https://www.mdpi.com/2079-4991/11/3/607

In this work, polymeric membranes functionalized with ionic liquids (ILs) and exfoliated graphene nanoplatelets (xGnP) were developed and characterized. These membranes based on graphene ionanofluids (IoNFs) are promising materials for gas separation. The stability of the selected IoNFs in the polymer membranes was determined by thermogravimetric analysis (TGA). The morphology of membranes was characterized using scanning electron microscope (SEM) and interferometric optical profilometry (WLOP). SEM results evidence that upon the small addition of xGnP into the IL-dominated environment, the interaction between IL and xGnP facilitates the migration of xGnP to the surface, while suppressing the interaction between IL and Pebax^®1657. Fourier transform infrared spectroscopy (FTIR) was also used to determine the polymer–IoNF interactions and the distribution of the IL in the polymer matrix. Finally, the thermodynamic properties and phase transitions (polymer–IoNF) of these functionalized membranes were studied using differential scanning calorimetry (DSC). This analysis showed a gradual decrease in the melting point of the polyamide (PA6) blocks with a decrease in the corresponding melting enthalpy and a complete disappearance of the crystallinity of the polyether (PEO) phase with increasing IL content. This evidences the high compatibility and good mixing of the polymer and the IoNF.