Charge-discharge behavior of fluorine-intercalated graphite for the positive electrode of fluoride ion shuttle battery
Fluorine-intercalated graphite, CxF with x = 2.8, was tested for the cathode active material of an all-solid-fluoride-ion shuttle battery. The addition of copper fluoride facilitated the discharge reaction of CxF. It was discharged up to 0.4 V vs. Pb and the resulting carbon was charged up to 1.6 V,...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2020-01-01
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| Series: | Electrochemistry Communications |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1388248119302899 |
| Summary: | Fluorine-intercalated graphite, CxF with x = 2.8, was tested for the cathode active material of an all-solid-fluoride-ion shuttle battery. The addition of copper fluoride facilitated the discharge reaction of CxF. It was discharged up to 0.4 V vs. Pb and the resulting carbon was charged up to 1.6 V, regenerating C-F bonding. A highest capacity of 230 mAh g−1 was delivered when 80 wt% (67 mol%) of CuF2 was added and utilization of CxF reached 98%. Keywords: Fluorine-intercalated graphite, Copper fluoride, All-solid-fluoride-ion shuttle battery, Positive electrode |
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| ISSN: | 1388-2481 |