N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine

N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine

The title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile. The fluorene ring system is substantially planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedr...

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Main Authors: Zhong-Yuan Li, Peng Wang, Xia Chen
Format: Article
Language:English
Published: International Union of Crystallography 2014-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813033424
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spelling doaj-fa589a8f7fa34e368b9a833ac24337fe2020-11-24T21:30:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-01-01701o59o6010.1107/S1600536813033424sj5378N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamineZhong-Yuan Li0Peng Wang1Xia Chen2School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, People's Republic of ChinaSchool of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, People's Republic of ChinaSchool of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, People's Republic of ChinaThe title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile. The fluorene ring system is substantially planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-methoxybenzylamine ring plane. In the crystal, molecules are linked by N—H...π and C—H...π interactions, which leads to the formation of two-dimensional network lying parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S1600536813033424
collection DOAJ
language English
format Article
sources DOAJ
author Zhong-Yuan Li
Peng Wang
Xia Chen
spellingShingle Zhong-Yuan Li
Peng Wang
Xia Chen
N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
Acta Crystallographica Section E
author_facet Zhong-Yuan Li
Peng Wang
Xia Chen
author_sort Zhong-Yuan Li
title N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
title_short N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
title_full N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
title_fullStr N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
title_full_unstemmed N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
title_sort n-[(9h-fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-01-01
description The title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile. The fluorene ring system is substantially planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-methoxybenzylamine ring plane. In the crystal, molecules are linked by N—H...π and C—H...π interactions, which leads to the formation of two-dimensional network lying parallel to the bc plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813033424
work_keys_str_mv AT zhongyuanli n9hfluoren9ylidene2methoxyphenylmethyl111trimethylsilanamine
AT pengwang n9hfluoren9ylidene2methoxyphenylmethyl111trimethylsilanamine
AT xiachen n9hfluoren9ylidene2methoxyphenylmethyl111trimethylsilanamine
_version_ 1725960911269658624

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