2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole

2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole

The title compound, C16H18N4S2, was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis(bromomethyl)-2,5-dimethylbenzene. The molecule is located on a crystallographic centre of inversion and therefore adopts a trans configuration...

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Bibliographic Details
Main Authors: Malcolm J. Applewhite, Storm V. Potts
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810039607
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spelling doaj-fa42e23050fe4ec4bf68815bc05ab3482020-11-25T00:50:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611o2749o274910.1107/S16005368100396072-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazoleMalcolm J. ApplewhiteStorm V. PottsThe title compound, C16H18N4S2, was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis(bromomethyl)-2,5-dimethylbenzene. The molecule is located on a crystallographic centre of inversion and therefore adopts a trans configuration with regards to the orientation of the two sulfur atoms. An intermolecular N—H...N hydrogen bond forms layers of molecules parallel to (overline{1}03). The dihedral angle between the central and terminal rings is 174.8 (2)°. http://scripts.iucr.org/cgi-bin/paper?S1600536810039607
collection DOAJ
language English
format Article
sources DOAJ
author Malcolm J. Applewhite
Storm V. Potts
spellingShingle Malcolm J. Applewhite
Storm V. Potts
2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
Acta Crystallographica Section E
author_facet Malcolm J. Applewhite
Storm V. Potts
author_sort Malcolm J. Applewhite
title 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_short 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_full 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_fullStr 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_full_unstemmed 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_sort 2-({4-[(1h-imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1h-imidazole
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description The title compound, C16H18N4S2, was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis(bromomethyl)-2,5-dimethylbenzene. The molecule is located on a crystallographic centre of inversion and therefore adopts a trans configuration with regards to the orientation of the two sulfur atoms. An intermolecular N—H...N hydrogen bond forms layers of molecules parallel to (overline{1}03). The dihedral angle between the central and terminal rings is 174.8 (2)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810039607
work_keys_str_mv AT malcolmjapplewhite 241himidazol2ylsulfanylmethyl25dimethylbenzylsulfanyl1himidazole
AT stormvpotts 241himidazol2ylsulfanylmethyl25dimethylbenzylsulfanyl1himidazole
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