Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh<sub>3</sub>)(Br)]<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>, [Pd(Br)]<sub>2</sub>(μ,η<sup>2</sup>-Hdppa)<sub>2</sub>, and [{Pd(PPh<sub>3</sub>)(CH<sub>3</sub>CN)}<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>][BF<sub>4</sub>]<sub>2</sub>

Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh<sub>3</sub>)(Br)]<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>, [Pd(Br)]<sub>2</sub>(μ,η<sup>2</sup>-Hdppa)<sub>2</sub>, and [{Pd(PPh<sub>3</sub>)(CH<sub>3</sub>CN)}<sub>2</sub>(μ,η<sup>2</sup>-C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>)<sub>2</sub>][BF<sub>4</sub>]<sub>2</sub>

In a refluxing chloroform solution<b>, </b>the η<sup>1</sup>-pyrimidinyl {pyrimidinyl = C<sub>4</sub>H<sub>3</sub>N<sub>2</sub>} palladium complex [Pd(PPh<sub>3</sub>)<sub>2</sub>(η<sup>1</sup>-C<sub&g...

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Bibliographic Details
Main Authors: Hsiao-Fen Wang, Kuang-Hway Yih, Gene-Hsiang Lee
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Molecules
Subjects:
<b>Keywords: </b>dipalladium
pyrimidinyl
tris(pyrazoyl-1-yl)borate
pyrrolidinyldithiocarbamate
doubly bridged
crystal structures
Online Access:https://www.mdpi.com/1420-3049/25/9/2035

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