A PCBM-Modified TiO2 Blocking Layer towards Efficient Perovskite Solar Cells
Organometal halide perovskite as a promising absorber in solar cells has caught tremendous attention in the past few years. Herein, a hydrophobic PCBM layer was introduced into planar heterojunction perovskite solar cells to form the TiO2/PCBM double blocking layer. The bilayer structure assures the...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Hindawi Limited
2017-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/2017/2562968 |
| Summary: | Organometal halide perovskite as a promising absorber in solar cells has caught tremendous attention in the past few years. Herein, a hydrophobic PCBM layer was introduced into planar heterojunction perovskite solar cells to form the TiO2/PCBM double blocking layer. The bilayer structure assures the formation of a dense, smooth, and pinhole-free blocking layer. And the PCBM layer can also be in favor of larger grain size perovskite film and further passivate the TiO2 blocking layer. Scanning electron microscope, atomic force microscope, and X-ray diffraction (XRD) results suggest the formation of a uniform and compact CH3NH3PbI3−xClx perovskite layer on the PCBM-modified TiO2 blocking layer. The solar cell has reached a PCE up to 16.37%, which is greatly larger than the control device with a PCE of 10.81%. |
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| ISSN: | 1110-662X 1687-529X |