Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate

Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate

In the title mononuclear iron(III) complex, [Fe(C15H13N2O3)2]Cl·H2O, the FeIII atom has a distorted octahedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl− anions and water molecules ar...

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Main Authors: Li-Fei Zou, Yu-Qin Ma, Gui-Miao Yu, Feng-Jiao Gan, Yun-Hui Li
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810023226
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spelling doaj-f98ce0789d894dd4b343abe2afec54ae2020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m828m82810.1107/S1600536810023226Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrateLi-Fei ZouYu-Qin MaGui-Miao YuFeng-Jiao GanYun-Hui LiIn the title mononuclear iron(III) complex, [Fe(C15H13N2O3)2]Cl·H2O, the FeIII atom has a distorted octahedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl− anions and water molecules are connected into a chain along [100] through N—H...O, O—H...Cl and N—H...Cl hydrogen bonds. Two adjacent chains are linked by O—H...O hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536810023226
collection DOAJ
language English
format Article
sources DOAJ
author Li-Fei Zou
Yu-Qin Ma
Gui-Miao Yu
Feng-Jiao Gan
Yun-Hui Li
spellingShingle Li-Fei Zou
Yu-Qin Ma
Gui-Miao Yu
Feng-Jiao Gan
Yun-Hui Li
Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate
Acta Crystallographica Section E
author_facet Li-Fei Zou
Yu-Qin Ma
Gui-Miao Yu
Feng-Jiao Gan
Yun-Hui Li
author_sort Li-Fei Zou
title Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate
title_short Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate
title_full Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate
title_fullStr Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate
title_full_unstemmed Bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(III) chloride monohydrate
title_sort bis{2-[(2-benzoylhydrazin-1-ylidene)methyl]-6-methoxyphenolato}iron(iii) chloride monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description In the title mononuclear iron(III) complex, [Fe(C15H13N2O3)2]Cl·H2O, the FeIII atom has a distorted octahedral geometry and is six-coordinated by four O atoms and two N atoms from two ligands. In the crystal structure, the complex cations, Cl− anions and water molecules are connected into a chain along [100] through N—H...O, O—H...Cl and N—H...Cl hydrogen bonds. Two adjacent chains are linked by O—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810023226
work_keys_str_mv AT lifeizou bis22benzoylhydrazin1ylidenemethyl6methoxyphenolatoironiiichloridemonohydrate
AT yuqinma bis22benzoylhydrazin1ylidenemethyl6methoxyphenolatoironiiichloridemonohydrate
AT guimiaoyu bis22benzoylhydrazin1ylidenemethyl6methoxyphenolatoironiiichloridemonohydrate
AT fengjiaogan bis22benzoylhydrazin1ylidenemethyl6methoxyphenolatoironiiichloridemonohydrate
AT yunhuili bis22benzoylhydrazin1ylidenemethyl6methoxyphenolatoironiiichloridemonohydrate
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