4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione

4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione

The title compound, C19H15NO2S3, is the first example of a dithia analogue of pyrano[3,4-b]indolone. The almost planar thiopyranoindolethione ring system (r.m.s. deviation for all non-H atoms = 0.030 Å) makes a dihedral angle of 80.70 (8)° with t...

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Main Authors: Heiner Detert, Dieter Schollmeyer, Bernhard Witulski, Benjamin Dassonneville
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810038201
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spelling doaj-f9281d344d6d4deca89b5620712512352020-11-24T22:09:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610o2665o266510.1107/S16005368100382014-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thioneHeiner DetertDieter SchollmeyerBernhard WitulskiBenjamin DassonnevilleThe title compound, C19H15NO2S3, is the first example of a dithia analogue of pyrano[3,4-b]indolone. The almost planar thiopyranoindolethione ring system (r.m.s. deviation for all non-H atoms = 0.030 Å) makes a dihedral angle of 80.70 (8)° with the p-tolyl ring. In the crystal, molecules are connected via C—H...O hydrogen bonds into two chains along the b axis. These chains are connected via π–π interactions between symmetry-related thiopyranoindolethione ring systems [centroid–centroid distance = 3.588 (1) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536810038201
collection DOAJ
language English
format Article
sources DOAJ
author Heiner Detert
Dieter Schollmeyer
Bernhard Witulski
Benjamin Dassonneville
spellingShingle Heiner Detert
Dieter Schollmeyer
Bernhard Witulski
Benjamin Dassonneville
4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione
Acta Crystallographica Section E
author_facet Heiner Detert
Dieter Schollmeyer
Bernhard Witulski
Benjamin Dassonneville
author_sort Heiner Detert
title 4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione
title_short 4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione
title_full 4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione
title_fullStr 4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione
title_full_unstemmed 4-Methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9H)-thione
title_sort 4-methyl-9-[(4-methylphenyl)sulfonyl]thiopyrano[3,4-b]indole-3(9h)-thione
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-10-01
description The title compound, C19H15NO2S3, is the first example of a dithia analogue of pyrano[3,4-b]indolone. The almost planar thiopyranoindolethione ring system (r.m.s. deviation for all non-H atoms = 0.030 Å) makes a dihedral angle of 80.70 (8)° with the p-tolyl ring. In the crystal, molecules are connected via C—H...O hydrogen bonds into two chains along the b axis. These chains are connected via π–π interactions between symmetry-related thiopyranoindolethione ring systems [centroid–centroid distance = 3.588 (1) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536810038201
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AT dieterschollmeyer 4methyl94methylphenylsulfonylthiopyrano34bindole39hthione
AT bernhardwitulski 4methyl94methylphenylsulfonylthiopyrano34bindole39hthione
AT benjamindassonneville 4methyl94methylphenylsulfonylthiopyrano34bindole39hthione
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