Synthesis and characterisation of organotin(IV) derivatives of ambidentate ligands containing nitrogen and sulphur donor atoms

Synthesis and characterisation of organotin(IV) derivatives of ambidentate ligands containing nitrogen and sulphur donor atoms

A series of organotin(IV) derivatives of bis(pyrimidin-2-ylthio)methane (ptm), 1,2-bis(pyrimidin-2-ylthio)ethane (pte) and 1,6-bis(pyrimidin-2-ylthio)hexane (pth) have been prepared in dichloromethane at room temperature. The 2:1 (M/L) molar ratio compounds have a general formula of [Sn2ClxPh8-xL] (...

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Bibliographic Details
Main Authors: Chagas Rafael César Russo, da Silveira Maia José Roberto, Ferraz Vany P.
Format: Article
Language:English
Published: De Gruyter 2011-12-01
Series:Main Group Metal Chemistry
Subjects:
bis(pyrimidin-2-ylthio)alkane
gel permeation chromatography (gpc)
infrared
organotin
polyfunctional ligands
119sn nmr
Online Access:https://doi.org/10.1515/mgmc-2012-0904

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