Poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]

In the title complex, [Pr(C6H4NO3)(C2O4)(H2O)2]n, each PrIII ion is coordinated by eight O atoms from two 2-oxynicotinate ligands, two oxalate ligands and two water molecules, displaying a distorted bicapped square-antiprismatic geometry. The carboxylate groups link adjacent praseodymium metal centr...

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Format: Article
Language:English
Published: International Union of Crystallography 2009-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680900542X
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spelling doaj-f8b019836743455d8c0fa9366c190cdc2020-11-25T01:10:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m310m31010.1107/S160053680900542XPoly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]In the title complex, [Pr(C6H4NO3)(C2O4)(H2O)2]n, each PrIII ion is coordinated by eight O atoms from two 2-oxynicotinate ligands, two oxalate ligands and two water molecules, displaying a distorted bicapped square-antiprismatic geometry. The carboxylate groups link adjacent praseodymium metal centres, forming layers parallel to the bc plane. The crystal packing is stabilized by intermolecular O—H...O and N—H...O hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S160053680900542X
collection DOAJ
language English
format Article
sources DOAJ
title Poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]
spellingShingle Poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]
Acta Crystallographica Section E
title_short Poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]
title_full Poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]
title_fullStr Poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]
title_full_unstemmed Poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(III)]
title_sort poly[diaqua(μ-oxalato)(μ-2-oxidopyridinium-3-carboxylato)praseodymium(iii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-03-01
description In the title complex, [Pr(C6H4NO3)(C2O4)(H2O)2]n, each PrIII ion is coordinated by eight O atoms from two 2-oxynicotinate ligands, two oxalate ligands and two water molecules, displaying a distorted bicapped square-antiprismatic geometry. The carboxylate groups link adjacent praseodymium metal centres, forming layers parallel to the bc plane. The crystal packing is stabilized by intermolecular O—H...O and N—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S160053680900542X
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