Dilute Ionic Liquids Pretreatment of Palm Empty Bunch and Its Impact to Produce Bioethanol

• Main Authors: Lucy Arianie, Utin Dewi Pebriyana, Yudiansyah Yudiansyah, Nora Idiawati, Deana Wahyuningrum
• Format: Article
• Language: English
• Published: University of Brawijaya 2013-12-01
• Series: Journal of Pure and Applied Chemistry Research
• Subjects: applied chemistry
• Online Access: http://www.jpacr.ub.ac.id/index.php/jpacr/article/view/165

Ethanol production through ionic liquids pretreatment of palm empty bunch (PEB) was carried out. This research aims to investigate impact of ionic liquids synthetic i.e 1-butyl-3-methyl imidazoliumbromide or [BMIM]bromide toward cellulose’s palm empty bunch and convert its cellulose into bioethanol. Ionic liquid was synthesized  through reflux and microwave assisted synthesis methods. Research investigation showed that microwave assisted synthesis produce [BMIM]bromide 90% faster than reflux method. The characterization of synthesized product using FTIR, ¹H-NMR, ¹³C-NMR and LC-MS showed that these reactions have been carried out successfully. Scanning electron microscope figure out changes morphological surface of palm empty bunch caused by ionic liquid pretreatment. Crystallinity index of PEB milled and cellulose of PEFB after [BMIM]bromide dissolution were identified using comparison of PEB FTIR spectrum. Cellulose without dilute [BMIM]bromide have higher LOI number than cellulose after [BMIM]bromide dissolution. It indicated that a large part of cellulose after dissolution has been changed into amorf. Hydrolysis residue of palm empty bunch hydrolyzed by sulfuric acids 5%, 100 ⁰C for 5 hours and produce 685 ppm of reducing sugar. Simultaneous Saccharification and Fermentation using Trichoderma viride and Saccharomyce cerevisiae  for 5 days produce 0,69% of bioethanol.