Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate

Crystal structure and photoluminescent properties of bis(4′-chloro-2,2′:6′,2′′-terpyridyl)cobalt(II) dichloride tetrahydrate

In the title hydrated complex, [Co(C15H10ClN3)2]Cl2·4H2O, the complete dication is generated by \overline{4} symmetry. The CoN6 moiety shows distortion from regular octahedral geometry with the trans bond angles of two N—Co—N units being 160.62 (9)°. In the crystal, O—H...Cl and C—H...O interactions...

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Bibliographic Details
Main Authors: B. Thippeswamy, P. A. Suchetan, K. M. Mahadevan, H. Nagabhushana, G. R. Vijayakumar
Format: Article
Language:English
Published: International Union of Crystallography 2020-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
2,2′,6′,2′′-terpyridine
photoluminescence
sem
tg–dta
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698902000287X

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