On the phosphate derivative of the Tchugaev salt

• Main Authors: A. B. Venediktov, S. V. Korenev, Yu. V. Shubin, S. A. Gromilov, P. E. Plyusnin, S. V. Tkachev, D. V. Vasilchenko
• Format: Article
• Language: Russian
• Published: MIREA - Russian Technological University 2010-12-01
• Series: Тонкие химические технологии
• Subjects: pt(iv) chloropentaammine phosphate; composition and yield of complex; structure of polycrystals; ¹⁹⁵pt and ¹⁴n spectra
• Online Access: https://www.finechem-mirea.ru/jour/article/view/910
• ISSN: 2410-6593; 2686-7575

Pt(IV) chloropentaammine phosphate was studied in details using IR and UV-Vis spectroscopy, X-ray powder diffraction, differential thermal and elemental analysis. Crystal structure of the complex was solved from powder diffraction data. 195Pt and 14N NMR spectra of [Pt(NH3)5Cl]3+cation were obtained and interpreted for the first time.