1,1,2,2,2,3,3,3-Octacarbonyl-1,1,2,3-tetrakis(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane-κP)-triangulo-triosmium(0)

1,1,2,2,2,3,3,3-Octacarbonyl-1,1,2,3-tetrakis(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane-κP)-triangulo-triosmium(0)

The title compound, [Os3(C6H12N3P)4(CO)8], crystallizes in the orthorhombic space group Pbca with Z = 8. The molecule consists of a triangular triosmium(0) core surrounded by eight carbonyl ligands and four 1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane (or PTA) ligands. One Os atom is coordinated...

Full description

Bibliographic Details
Main Authors:	David M. Marolf, Kristen L. Brehm, Vincent M. Lynch, Gregory L. Powell
Format:	Article
Language:	English
Published:	International Union of Crystallography 2020-07-01
Series:	IUCrData
Subjects:	crystal structure osmium carbonyl trinuclear cluster pta ligands
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2414314620009359

Similar Items

1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane tetrafluoroborate
by: Armando J. L. Pombeiro, et al.
Published: (2008-03-01)

Bis(3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane) bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II)
by: Chen Pan, et al.
Published: (2011-06-01)

Crystal structure of 2-(tricyclo[3.3.1.13,7]decan-1-yl)-3-(tricyclo[3.3.1.13,7]- decan-1-ylimino)isoindolin-1-one, C28H34N2O
by: Ha Kwang
Published: (2013-03-01)

The crystal structure of tetrakis(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane-κP)silver(I) chloride dihydrate, C24H60AgClN12O6P4
by: Oosthuizen Runé, et al.
Published: (2017-09-01)

1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide
by: Armando J. L. Pombeiro, et al.
Published: (2008-02-01)

4-Nitro-2-{[(tricyclo[3.3.1.13,7]decan-1-yl)iminiumyl]methyl}phenolate
by: Kwang Ha
Published: (2012-04-01)

2-(Tricyclo[3.3.1.13,7]dec-2-ylamino)ethanol hemihydrate
by: Grant A. Boyle, et al.
Published: (2008-07-01)

A new polymorph of N-(prop-2-ynyl)tricyclo[3.3.1.13,7]decane-1-carboxamide
by: Wolfgang Frey, et al.
Published: (2008-08-01)

Synthesis of 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) complexes and the development of chromium salen catalysts for the copolymerization of CO2 and epoxides
by: Ortiz, Cesar Gabriel
Published: (2004)

(3aRS,4SR,7RS,7aSR)-2-(Tricyclo[3.3.1.13,7]decan-1-yl)-4,5,6,7-tetrahydro-4,7-epoxyisoindoline-1,3-dione
by: Zaiyou Tan, et al.
Published: (2010-06-01)

Synthesis of 1-cyano-2,3,7-triaza-bicyclo[3.3.0]oct-2-ene derivatives by substitution
by: Yin ,Shiu-Ping, et al.
Published: (1995)

Refinement of the crystal structure of 1,3,5,7-thioxo-2,4,6,8,9,10-hexathial, 1,3,5,7-tetraphosphatricyclo[3.3.1.13,7]decane, tetraphosphorus decasulfide, P4S10
by: Blachnik R., et al.
Published: (1998-04-01)

Crystal structure of bis(bis{μ3-3-methyl-3-[(4-nitro-2-oxidobenzylidene)amino]propane-1,3-diolato}tris[chlorido(dimethyl sulfoxide)iron(III)]) dimethyl sulfoxide heptasolvate dihydrate
by: Eduard Chygorin, et al.
Published: (2016-12-01)

Investigation of Solvatomorphism and Its Photophysical Implications for Archetypal Trinuclear Au<sub>3</sub>(1-Methylimidazolate)<sub>3</sub>
by: Shengyang Guan, et al.
Published: (2021-07-01)

Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives
by: Diop Tidiane, et al.
Published: (2013-07-01)

Crystal structures of trans-acetyldicarbonyl(η5-cyclopentadienyl)(1,3,5-triaza-7-phosphaadamantane)molybdenum(II) and trans-acetyldicarbonyl(η5-cyclopentadienyl)(3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)molybdenum(II)
by: Mitchell R. Anstey, et al.
Published: (2020-04-01)

Study on the pyrolysis of 2,3,7-triaza-bicyclo〔3.3.0〕oct-2-enes
by: Chen;Su-Jane, et al.
Published: (1993)

Study on photolysis of 2,3,7-triaza-bicyclo[3.3.0]oct-2-enes
by: Wang, Rui Xuan, et al.
Published: (1995)

(I) Study on photolysis of 2,3,7-triaza-bicyclo[3.3.0] oct-2- enes (II) Synthesis of 2,3,7-triaza-bicyclo[3.3.0]oct-2-ene derivatives by Michael addition
by: Wang ,Reuy-Shiuan, et al.
Published: (1995)

(1)The Preparation of Radiopharmaceutical for Dopamine Receptor D2 Imaging (2)A Further Study on Pyrolysis of 2,3,7-triaza- bicyclo[3.3.0] oct-2-enes
by: Hsu ,Hsing Wei, et al.
Published: (1996)

3-(1H-1,3-Benzimidazol-2-yl)-2,7-dimethoxyquinoline
by: Hayette Alliouche, et al.
Published: (2012-08-01)

10-(1,3-Benzothiazol-2-yl)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-pyrano[3,2-g]pyrido[3,2,1-hi]quinoline
by: Ki-Min Park, et al.
Published: (2010-04-01)

3-Bromo-7-methoxy-2-phenylimidazo[2,1-b][1,3]benzothiazole
by: Alexander S. Bunev, et al.
Published: (2013-04-01)

7-Nitro-1,2,3,4-tetrahydronaphthalene-1-spiro-2′-(1,3-dithiane)
by: Shyamaprosad Goswami, et al.
Published: (2009-02-01)

2-[(1R,3S)-6,7-Dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinolin-3-yl]-4-phenyl-1,3-thiazole
by: Glenn E. M. Maguire, et al.
Published: (2011-10-01)

(1S,3S)-Methyl 2-benzyl-6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate
by: Tricia Naicker, et al.
Published: (2011-06-01)

Crystal structures of 2′-benzoyl-1′-(4-methylphenyl)-1,1′,2,2′,5′,6′,7′,7a′-octahydrospiro[indole-3,3′-pyrrolizin]-2-one and 2′-(4-bromobenzoyl)-1′-(2-chlorophenyl)-1,1′,2,2′,5′,6′,7′,7a′-octahydrospiro[indole-3,3′-pyrrolizin]-2-one
by: M. Chandrarekha, et al.
Published: (2016-11-01)

7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
by: Jian Li, et al.
Published: (2014-06-01)

Biotransformation of trans-1,1,1,3-tetrafluoropropene, 2,3,3,3-tetrafluoropropene and 1,2,3,3,3-pentafluoropropene
by: Schuster, Paul Xaver
Published: (2009)

(1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate
by: Tricia Naicker, et al.
Published: (2011-06-01)

1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate
by: Wenzhen Guo, et al.
Published: (2016-02-01)

1,1,3,3,5,5,7,7-Octaphenyl-2,6-dioxa-4,8-diaza-1,3,5,7-tetrasilacyclooctane
by: Zhen Lv, et al.
Published: (2011-05-01)

（I）The influences of reaction conditions on preparations of 1-acetyl-7-(3-oxo- butyl)-2,3,7-triaza-bicyclo[3.3.0]oct-2-ene （II）Preparation of pinacol using TiCl4－Zn
by: Teng-Yi Hsu, et al.
Published: (2006)

1′-Allyl-1-(3,4-dimethylbenzoyl)-2-(4-methyl-1,3-thiazol-5-yl)-1,2,5,6,7,7a-hexahydrospiro[pyrrolizine-3,3′-indolin]-2′-one
by: V. Karthikeyan, et al.
Published: (2014-05-01)

Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexahydro-4,7-methano-2-benzothiophene 2,2-dioxide
by: Sambasivarao Kotha, et al.
Published: (2014-11-01)

3-(1,3-Dioxolan-2-yl)-2-hydrazino-7-methylquinoline
by: F. Nawaz Khan, et al.
Published: (2009-02-01)

(1R,3S)-Methyl 2-benzyl-6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate
by: Glenn E. M. Maguire, et al.
Published: (2009-12-01)

{(1R,3S)-2-Benzyl-6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinolin-3-yl}diphenylmethanol
by: Glenn E.M. Maguire, et al.
Published: (2010-03-01)

The volatile rare earth chelates of 1, 1, 1, 2, 2, 3, 3-heptafluoro-7, 7-dimethyl-4, 6-octanedione /
by: Springer, Charles Sinclair
Published: (1967)

Crystal structures of 2-bromo-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane and 2-bromo-1,1,1,3,3,3-hexaisopropyl-2-(triisopropylsilyl)trisilane
by: Eva M. Gulotty, et al.
Published: (2018-08-01)