Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)

Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)

The title complex, [Mn(C6H5N2O4)2(H2O)2], was obtained by hydrothermal synthesis. The MnII atom, which lies on an inversion centre, displays a slightly distorted octahedral geometry. In the crystal packing, complex molecules are linked by intermolecular O—H...O and N—H...O hydrog...

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Main Authors: Gan-Sheng Huang, Shao-Ming Ying, Jun-Yue Lin, Xiu-Guang Yi, Jian-Zhong Zeng
Format: Article
Language:English
Published: International Union of Crystallography 2008-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680800411X
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spelling doaj-f6c3d456acd7453a91cd98a5cfcb74282020-11-25T01:27:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-03-01643m476m47610.1107/S160053680800411XDiaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)Gan-Sheng HuangShao-Ming YingJun-Yue LinXiu-Guang YiJian-Zhong ZengThe title complex, [Mn(C6H5N2O4)2(H2O)2], was obtained by hydrothermal synthesis. The MnII atom, which lies on an inversion centre, displays a slightly distorted octahedral geometry. In the crystal packing, complex molecules are linked by intermolecular O—H...O and N—H...O hydrogen bonds to form a three-dimensional supramolecular structure. The title complex is isostructural with the corresponding cadmium(II) complex [Nie, Wen, Wu, Liu & Liu (2007). Acta Cryst. E63, m753–m755].http://scripts.iucr.org/cgi-bin/paper?S160053680800411X
collection DOAJ
language English
format Article
sources DOAJ
author Gan-Sheng Huang
Shao-Ming Ying
Jun-Yue Lin
Xiu-Guang Yi
Jian-Zhong Zeng
spellingShingle Gan-Sheng Huang
Shao-Ming Ying
Jun-Yue Lin
Xiu-Guang Yi
Jian-Zhong Zeng
Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)
Acta Crystallographica Section E
author_facet Gan-Sheng Huang
Shao-Ming Ying
Jun-Yue Lin
Xiu-Guang Yi
Jian-Zhong Zeng
author_sort Gan-Sheng Huang
title Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)
title_short Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)
title_full Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)
title_fullStr Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)
title_full_unstemmed Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II)
title_sort diaquabis(5-carboxy-2-methyl-1h-imidazole-4-carboxylato-κ2n3,o4)manganese(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-03-01
description The title complex, [Mn(C6H5N2O4)2(H2O)2], was obtained by hydrothermal synthesis. The MnII atom, which lies on an inversion centre, displays a slightly distorted octahedral geometry. In the crystal packing, complex molecules are linked by intermolecular O—H...O and N—H...O hydrogen bonds to form a three-dimensional supramolecular structure. The title complex is isostructural with the corresponding cadmium(II) complex [Nie, Wen, Wu, Liu & Liu (2007). Acta Cryst. E63, m753–m755].
url http://scripts.iucr.org/cgi-bin/paper?S160053680800411X
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AT junyuelin diaquabis5carboxy2methyl1himidazole4carboxylato9542n3o4manganeseii
AT xiuguangyi diaquabis5carboxy2methyl1himidazole4carboxylato9542n3o4manganeseii
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