On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond
Incorporating carbon-carbon triple bonds into conjugated chains typically requires acetylenic precursors. Here, the authors synthesize poly(p-phenylene ethynylene) molecular wires on Cu(111) by directly coupling trichloromethyl-containing precursors, forming C-C triple bonds in situ
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| Format: | Article |
| Language: | English |
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Nature Publishing Group
2018-06-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-04681-z |
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doaj-f6ab2c9a71404ec6b3cab7922d6242b32021-05-11T09:52:36ZengNature Publishing GroupNature Communications2041-17232018-06-01911710.1038/s41467-018-04681-zOn-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bondChen-Hui Shu0Meng-Xi Liu1Ze-Qi Zha2Jin-Liang Pan3Shao-Ze Zhang4Yu-Li Xie5Jian-Le Chen6Ding-Wang Yuan7Xiao-Hui Qiu8Pei-Nian Liu9Shanghai Key Laboratory of Functional Materials Chemistry, Key Laboratory for Advanced Materials, State Key Laboratory of Chemical Engineering and School of Chemistry and Molecular Engineering, East China University of Science and TechnologyCAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and TechnologyCAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and TechnologyCAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and TechnologyShanghai Key Laboratory of Functional Materials Chemistry, Key Laboratory for Advanced Materials, State Key Laboratory of Chemical Engineering and School of Chemistry and Molecular Engineering, East China University of Science and TechnologyShanghai Key Laboratory of Functional Materials Chemistry, Key Laboratory for Advanced Materials, State Key Laboratory of Chemical Engineering and School of Chemistry and Molecular Engineering, East China University of Science and TechnologyShanghai Key Laboratory of Functional Materials Chemistry, Key Laboratory for Advanced Materials, State Key Laboratory of Chemical Engineering and School of Chemistry and Molecular Engineering, East China University of Science and TechnologyCollege of Materials Science and Engineering, Hunan UniversityCAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and TechnologyShanghai Key Laboratory of Functional Materials Chemistry, Key Laboratory for Advanced Materials, State Key Laboratory of Chemical Engineering and School of Chemistry and Molecular Engineering, East China University of Science and TechnologyIncorporating carbon-carbon triple bonds into conjugated chains typically requires acetylenic precursors. Here, the authors synthesize poly(p-phenylene ethynylene) molecular wires on Cu(111) by directly coupling trichloromethyl-containing precursors, forming C-C triple bonds in situhttps://doi.org/10.1038/s41467-018-04681-z |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Chen-Hui Shu Meng-Xi Liu Ze-Qi Zha Jin-Liang Pan Shao-Ze Zhang Yu-Li Xie Jian-Le Chen Ding-Wang Yuan Xiao-Hui Qiu Pei-Nian Liu |
| spellingShingle |
Chen-Hui Shu Meng-Xi Liu Ze-Qi Zha Jin-Liang Pan Shao-Ze Zhang Yu-Li Xie Jian-Le Chen Ding-Wang Yuan Xiao-Hui Qiu Pei-Nian Liu On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond Nature Communications |
| author_facet |
Chen-Hui Shu Meng-Xi Liu Ze-Qi Zha Jin-Liang Pan Shao-Ze Zhang Yu-Li Xie Jian-Le Chen Ding-Wang Yuan Xiao-Hui Qiu Pei-Nian Liu |
| author_sort |
Chen-Hui Shu |
| title |
On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond |
| title_short |
On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond |
| title_full |
On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond |
| title_fullStr |
On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond |
| title_full_unstemmed |
On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond |
| title_sort |
on-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2018-06-01 |
| description |
Incorporating carbon-carbon triple bonds into conjugated chains typically requires acetylenic precursors. Here, the authors synthesize poly(p-phenylene ethynylene) molecular wires on Cu(111) by directly coupling trichloromethyl-containing precursors, forming C-C triple bonds in situ |
| url |
https://doi.org/10.1038/s41467-018-04681-z |
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