Dimethylammonium diaqua(pyridine-2,4-dicarboxylato-κ2N,O2)cuprate(II)

The asymmetric unit of the title compound, (C2H8N)2[Cu(C7H3NO4)2(H2O)2], contains one-half of a mononuclear [Cu(C7H3NO4)2(H2O)2]2− anion, one dimethylammonium cation and one aqua ligand. The CuII atom, lying on an inversion center, is coordinated by two symmetry-related N atoms and two...

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Bibliographic Details
Main Authors: Ji-Dong Wang, Shu-Min Han
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810002497
Description
Summary:The asymmetric unit of the title compound, (C2H8N)2[Cu(C7H3NO4)2(H2O)2], contains one-half of a mononuclear [Cu(C7H3NO4)2(H2O)2]2− anion, one dimethylammonium cation and one aqua ligand. The CuII atom, lying on an inversion center, is coordinated by two symmetry-related N atoms and two O atoms from one pyridine-2,4-dicarboxylate ligand and two symmetry-related aqua ligands and exhibits a distorted octahedral trans-[CuN2O4] coordination geometry. Multiple crystallographically independent O—H...O and N—H...O hydrogen bonds form a three-dimensional network in the crystal structure.
ISSN:1600-5368