cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)

cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)

The title compound, cis-[Re(C12H24O4P)Cl2O(C18H15P)], was prepared from the analogous trans isomer [Głowiak et al. (2000). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The ReV atom adopts a distorted octahedral coordination geometry. Besi...

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Main Authors: Andrzej Gniewek, Miłosz Siczek, Anna Skarżyńska
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812015565
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spelling doaj-f6657315bac64c0d815d9fe4c6835bf12020-11-25T02:19:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m605m60610.1107/S1600536812015565cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)Andrzej GniewekMiłosz SiczekAnna SkarżyńskaThe title compound, cis-[Re(C12H24O4P)Cl2O(C18H15P)], was prepared from the analogous trans isomer [Głowiak et al. (2000). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The ReV atom adopts a distorted octahedral coordination geometry. Besides being coordinated by the oxide and the butanolate O atoms, the ReV atom is coordinated by a pair of chloride ligands and two P atoms in cis positions with respect to each other. In the crystal, adjacent molecules are linked by weak C—H...Cl interactions, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812015565
collection DOAJ
language English
format Article
sources DOAJ
author Andrzej Gniewek
Miłosz Siczek
Anna Skarżyńska
spellingShingle Andrzej Gniewek
Miłosz Siczek
Anna Skarżyńska
cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)
Acta Crystallographica Section E
author_facet Andrzej Gniewek
Miłosz Siczek
Anna Skarżyńska
author_sort Andrzej Gniewek
title cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)
title_short cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)
title_full cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)
title_fullStr cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)
title_full_unstemmed cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2O,P]oxido(triphenylphosphane-κP)rhenium(V)
title_sort cis-dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ5-dioxaphospholan-2-yloxy)butan-2-olato-κ2o,p]oxido(triphenylphosphane-κp)rhenium(v)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description The title compound, cis-[Re(C12H24O4P)Cl2O(C18H15P)], was prepared from the analogous trans isomer [Głowiak et al. (2000). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The ReV atom adopts a distorted octahedral coordination geometry. Besides being coordinated by the oxide and the butanolate O atoms, the ReV atom is coordinated by a pair of chloride ligands and two P atoms in cis positions with respect to each other. In the crystal, adjacent molecules are linked by weak C—H...Cl interactions, forming a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812015565
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AT miamp322oszsiczek cisdichlorido23dimethyl34455tetramethyl132amp9555dioxaphospholan2yloxybutan2olatoamp9542opoxidotriphenylphosphaneamp954prheniumv
AT annaskaramp380yamp324ska cisdichlorido23dimethyl34455tetramethyl132amp9555dioxaphospholan2yloxybutan2olatoamp9542opoxidotriphenylphosphaneamp954prheniumv
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