Crystal structure and optical performance in bulk γ-InSe single crystals

High purity γ-phase InSe single crystals have been synthesized and characterized by XRD, SEM, EDS and TEM. Detailed temperature dependent Raman and photoluminescence spectroscopy suggests a small blue-shift as temperature decreases. The corresponding blue shift in Raman and photoluminescence can be...

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Main Authors: Min Wu, Qiyun Xie, Yizhang Wu, Jiajin Zheng, Wei Wang, Liang He, Xiaoshan Wu, Bin Lv
Format: Article
Language:English
Published: AIP Publishing LLC 2019-02-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5086492
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spelling doaj-f605d802a6fb41a29a83094bb3b8a2032020-11-24T23:59:33ZengAIP Publishing LLCAIP Advances2158-32262019-02-0192025013025013-610.1063/1.5086492024902ADVCrystal structure and optical performance in bulk γ-InSe single crystalsMin Wu0Qiyun Xie1Yizhang Wu2Jiajin Zheng3Wei Wang4Liang He5Xiaoshan Wu6Bin Lv7Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing University of Posts & Telecommunications, Nanjing 210023, ChinaKey Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing University of Posts & Telecommunications, Nanjing 210023, ChinaNational Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, ChinaKey Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing University of Posts & Telecommunications, Nanjing 210023, ChinaJiangsu Provincial Key Laboratory of Advanced Photonic and Electronic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Electronic Science and Engineering, Nanjing University, Nanjing 210093, ChinaJiangsu Provincial Key Laboratory of Advanced Photonic and Electronic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Electronic Science and Engineering, Nanjing University, Nanjing 210093, ChinaNational Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, ChinaDepartment of Applied Physics, Zhejiang University of Technology, Hangzhou 310023, ChinaHigh purity γ-phase InSe single crystals have been synthesized and characterized by XRD, SEM, EDS and TEM. Detailed temperature dependent Raman and photoluminescence spectroscopy suggests a small blue-shift as temperature decreases. The corresponding blue shift in Raman and photoluminescence can be explained in terms of self-energy and the lattice parameter change induced variation of band gap, respectively. Moreover, bulk InSe exhibits photoresponsivity in a wide spectrum from 400 to 990 nm. The maximum photoresponsivity reaches up to 8.82 mA/W under the wavelength of 800 nm, which is consistent with high absorption at the wavelength.http://dx.doi.org/10.1063/1.5086492
collection DOAJ
language English
format Article
sources DOAJ
author Min Wu
Qiyun Xie
Yizhang Wu
Jiajin Zheng
Wei Wang
Liang He
Xiaoshan Wu
Bin Lv
spellingShingle Min Wu
Qiyun Xie
Yizhang Wu
Jiajin Zheng
Wei Wang
Liang He
Xiaoshan Wu
Bin Lv
Crystal structure and optical performance in bulk γ-InSe single crystals
AIP Advances
author_facet Min Wu
Qiyun Xie
Yizhang Wu
Jiajin Zheng
Wei Wang
Liang He
Xiaoshan Wu
Bin Lv
author_sort Min Wu
title Crystal structure and optical performance in bulk γ-InSe single crystals
title_short Crystal structure and optical performance in bulk γ-InSe single crystals
title_full Crystal structure and optical performance in bulk γ-InSe single crystals
title_fullStr Crystal structure and optical performance in bulk γ-InSe single crystals
title_full_unstemmed Crystal structure and optical performance in bulk γ-InSe single crystals
title_sort crystal structure and optical performance in bulk γ-inse single crystals
publisher AIP Publishing LLC
series AIP Advances
issn 2158-3226
publishDate 2019-02-01
description High purity γ-phase InSe single crystals have been synthesized and characterized by XRD, SEM, EDS and TEM. Detailed temperature dependent Raman and photoluminescence spectroscopy suggests a small blue-shift as temperature decreases. The corresponding blue shift in Raman and photoluminescence can be explained in terms of self-energy and the lattice parameter change induced variation of band gap, respectively. Moreover, bulk InSe exhibits photoresponsivity in a wide spectrum from 400 to 990 nm. The maximum photoresponsivity reaches up to 8.82 mA/W under the wavelength of 800 nm, which is consistent with high absorption at the wavelength.
url http://dx.doi.org/10.1063/1.5086492
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