Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2

Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2

Great progress has been made in topochemistry of mobile oxygen anions, but metastable compounds have not yet been achieved by deintercalation of sulfur anions. Here, the authors prepare metastable oxychalcogenide phases by taking advantage of redox-reactive sulfur dimers embedded in a layered oxysul...

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Main Authors: Shunsuke Sasaki, Maria Teresa Caldes, Catherine Guillot-Deudon, Isabelle Braems, Gwladys Steciuk, Lukáš Palatinus, Eric Gautron, Gilles Frapper, Etienne Janod, Benoît Corraze, Stéphane Jobic, Laurent Cario
Format: Article
Language:English
Published: Nature Publishing Group 2021-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-021-23677-w
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spelling doaj-f5f9230e3bc84a528235809c1086a3cb2021-06-20T11:12:27ZengNature Publishing GroupNature Communications2041-17232021-06-011211810.1038/s41467-021-23677-wDesign of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2Shunsuke Sasaki0Maria Teresa Caldes1Catherine Guillot-Deudon2Isabelle Braems3Gwladys Steciuk4Lukáš Palatinus5Eric Gautron6Gilles Frapper7Etienne Janod8Benoît Corraze9Stéphane Jobic10Laurent Cario11Université de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNInstitute of Physics ASCR, v.v.i.Institute of Physics ASCR, v.v.i.Université de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNInstitut de Chimie des Milieux et Matériaux de PoitiersUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMNGreat progress has been made in topochemistry of mobile oxygen anions, but metastable compounds have not yet been achieved by deintercalation of sulfur anions. Here, the authors prepare metastable oxychalcogenide phases by taking advantage of redox-reactive sulfur dimers embedded in a layered oxysulfide.https://doi.org/10.1038/s41467-021-23677-w
collection DOAJ
language English
format Article
sources DOAJ
author Shunsuke Sasaki
Maria Teresa Caldes
Catherine Guillot-Deudon
Isabelle Braems
Gwladys Steciuk
Lukáš Palatinus
Eric Gautron
Gilles Frapper
Etienne Janod
Benoît Corraze
Stéphane Jobic
Laurent Cario
spellingShingle Shunsuke Sasaki
Maria Teresa Caldes
Catherine Guillot-Deudon
Isabelle Braems
Gwladys Steciuk
Lukáš Palatinus
Eric Gautron
Gilles Frapper
Etienne Janod
Benoît Corraze
Stéphane Jobic
Laurent Cario
Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
Nature Communications
author_facet Shunsuke Sasaki
Maria Teresa Caldes
Catherine Guillot-Deudon
Isabelle Braems
Gwladys Steciuk
Lukáš Palatinus
Eric Gautron
Gilles Frapper
Etienne Janod
Benoît Corraze
Stéphane Jobic
Laurent Cario
author_sort Shunsuke Sasaki
title Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_short Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_full Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_fullStr Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_full_unstemmed Design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in La2O2S2
title_sort design of metastable oxychalcogenide phases by topochemical (de)intercalation of sulfur in la2o2s2
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2021-06-01
description Great progress has been made in topochemistry of mobile oxygen anions, but metastable compounds have not yet been achieved by deintercalation of sulfur anions. Here, the authors prepare metastable oxychalcogenide phases by taking advantage of redox-reactive sulfur dimers embedded in a layered oxysulfide.
url https://doi.org/10.1038/s41467-021-23677-w
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