Poly[aquabis(μ4-naphthalene-1,4-dicarboxylato)(1,10-phenanthroline-5,6-dione)dimanganese(II)]

Poly[aquabis(μ4-naphthalene-1,4-dicarboxylato)(1,10-phenanthroline-5,6-dione)dimanganese(II)]

The three-dimensional coordination polymer, [Mn2(C12H6O4)2(C12H6N2O2)(H2O)]n, features a water-coordinated MnII ion and an N-heterocycle-chelated MnII ion, both in six-coordinate octahedral geometries. Of the two rigid dianions, one is bonded to four MnII ions, with each of the O atoms being connect...

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Bibliographic Details
Main Authors: Zhen Wei, Feng-Yang Yu, Fang-Di Cong, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809046388
Description
Summary:The three-dimensional coordination polymer, [Mn2(C12H6O4)2(C12H6N2O2)(H2O)]n, features a water-coordinated MnII ion and an N-heterocycle-chelated MnII ion, both in six-coordinate octahedral geometries. Of the two rigid dianions, one is bonded to four MnII ions, with each of the O atoms being connected to a different metal ion. The other dianion uses one carboxylate group to chelate to one MnII ion and its other carboxylate group to bind to two MnII ions.
ISSN:1600-5368

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