Open questions on the reactivity of Criegee intermediates

Criegee intermediates are reactive intermediates formed in Earth’s atmosphere through ozonolysis of alkenes. Here the authors outline the fundamental chemistry that influences their highly conformer- and substituent-dependent unimolecular and bimolecular reactivity, and discuss open questions of fun...

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Main Authors:	Rebecca L. Caravan, Michael F. Vansco, Marsha I. Lester
Format:	Article
Language:	English
Published:	Nature Publishing Group 2021-03-01
Series:	Communications Chemistry
Online Access:	https://doi.org/10.1038/s42004-021-00483-5

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spelling	doaj-f5d17861992a4ff9a5b04c4775fc09b12021-03-28T11:05:40ZengNature Publishing GroupCommunications Chemistry2399-36692021-03-01411410.1038/s42004-021-00483-5Open questions on the reactivity of Criegee intermediatesRebecca L. Caravan0Michael F. Vansco1Marsha I. Lester2Chemical Sciences and Engineering Division, Argonne National LaboratoryChemical Sciences and Engineering Division, Argonne National LaboratoryDepartment of Chemistry, University of PennsylvaniaCriegee intermediates are reactive intermediates formed in Earth’s atmosphere through ozonolysis of alkenes. Here the authors outline the fundamental chemistry that influences their highly conformer- and substituent-dependent unimolecular and bimolecular reactivity, and discuss open questions of fundamental and atmospheric interest.https://doi.org/10.1038/s42004-021-00483-5
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Rebecca L. Caravan Michael F. Vansco Marsha I. Lester
spellingShingle	Rebecca L. Caravan Michael F. Vansco Marsha I. Lester Open questions on the reactivity of Criegee intermediates Communications Chemistry
author_facet	Rebecca L. Caravan Michael F. Vansco Marsha I. Lester
author_sort	Rebecca L. Caravan
title	Open questions on the reactivity of Criegee intermediates
title_short	Open questions on the reactivity of Criegee intermediates
title_full	Open questions on the reactivity of Criegee intermediates
title_fullStr	Open questions on the reactivity of Criegee intermediates
title_full_unstemmed	Open questions on the reactivity of Criegee intermediates
title_sort	open questions on the reactivity of criegee intermediates
publisher	Nature Publishing Group
series	Communications Chemistry
issn	2399-3669
publishDate	2021-03-01
description	Criegee intermediates are reactive intermediates formed in Earth’s atmosphere through ozonolysis of alkenes. Here the authors outline the fundamental chemistry that influences their highly conformer- and substituent-dependent unimolecular and bimolecular reactivity, and discuss open questions of fundamental and atmospheric interest.
url	https://doi.org/10.1038/s42004-021-00483-5
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Open questions on the reactivity of Criegee intermediates

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